Three novel thin-film composite (TFC) nanofiltration membranes are prepared using an ultrafiltration membrane (UFM) of organic polymer resin polyacrylonitrile followed by a mineralization process. The UFM was hydrolyzed (H-UFM) and then transferred in dopamine (DA) and tris buffer (TRIS) solutions. DA–TRIS coating is further favorable for the growth of nanoparticles (NPs), titania (TiO2), and zirconia (ZrO2) on membrane piece surface. A scanning electron microscope (SEM) was combined with an energy-dispersive spectrometer (EDS) in order to provide important insights into the arrangement and potential functions of NPs, due to their unambiguous chemical signal, for possible characterization and modification of materials at the atomic scale. Depending on whether the top layer is made of TiO2, ZrO2, or both, the membranes are called, respectively, TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon. The three membranes under the optimized preparation conditions (30 °C, 12 h of hydrolysis time, and operating pressure of 0.6 MPa) exhibited high rejection and permeation performance. TFC-NFTitanZircon showed the highest rejection (89–95%) for divalent cations with the salt rejection sequence of , while the permeate flux is not less than . All three membranes demonstrated long-term durability under 120-h testing.
Thin-film composite nanofiltration membrane (NFM) for salt rejection.
Novel in situ NFM fabrication using the insights provided by a scanning electron microscope combined with an energy-dispersive spectrometer on the arrangement and potential functions of nanoparticles.
Modification of an ultrafiltration membrane to the NFM for salt removal.
Organic–inorganic NF preparation using a mineralization process.
Nanofiltration (NF) is a pressure-driven process with properties lying between those of ultrafiltration (UF) and reverse osmosis (RO) (Nazia et al. 2020). The NF process was first explored during the late 1980s (Siddique et al. 2020; Yang et al. 2020b). Many things have changed over time; for example, the transmembrane pressure for NF membranes (NFMs) was initially in the range of 5–20 bar (Amirilargani et al. 2016) and nowadays can reach 40 bar (Marchetti et al. 2014). A variety of advantages such as low transmembrane pressure, high permeation flux, and high retention rate toward multivalent salts, and low investment (in comparison with the RO process) made NF to be used in various areas (Li et al. 2011; Luo & Wan 2013; Zinadini et al. 2017; Guo et al. 2020; Mi et al. 2020). Nowadays, different methods are used to prepare or modify NFMs. Among these techniques, interfacial polymerization (Yuan et al. 2020), nanoparticle (NP) incorporation (Singh & Mehata 2020), UV treatment (Nigiz & Kibar 2020), and layer-by-layer process (Guo et al. 2020) are more and more explored. All the methods used in the NF process aimed at developing membranes with higher selectivity, better rejection tendency, higher permeation flux, and also overcoming sometimes fouling issues. Despite the significant development of the NF process in laboratories and water treatment plants, there are still some issues to be addressed. To improve NFM utilization, Van der Bruggen et al. have studied several membrane parameters such as membrane lifetime and chemical resistance, membrane fouling, and membrane rejection (Van der Bruggen et al. 2008).
Most of the ideal NFMs are thin-film composite (TFC) membranes with support and a thin-film selective layer (Zhang et al. 2014a, 2014b; Lv et al. 2016; Zhao et al. 2020a, 2020b). Organic–inorganic TFC-NFMs have usually been synthesized by dispersing inorganic fillers in the polymer selective layer through blending, the sol–gel method, or in situ formation (Spijksma et al. 2006; Zheng et al. 2011; Vinh-Thang & Kaliaguine 2013; Fukumoto et al. 2014; Siddique et al. 2014; Jeon & Lee 2020; Karami et al. 2020). To successfully manufacture this type of membrane, a judicious choice of the organic support, of the inorganic NPs, and of what would play the role of ‘bio-glue’ for good adhesion between the substrate and the inorganic top layer is essential. In this study, as an organic substrate, a UF membrane polyacrylonitrile (PAN) has been used; and for inorganic NPs, both dioxide of titanium (TiO2) and dioxide of zirconium (ZrO2) have been chosen.
NPs have received much attention recently due to their unique properties in terms of catalytic activity, photoemission, and antimicrobial. NP-incorporated membranes have gained attention due to their ability to increase membrane permeability, mechanical properties, hydrophilicity, and selectivity in some cases. The NPs, which are commonly reported in NFMs fabrication, are ZrO2, TiO2, silica (SiO2), silver, and zinc oxide (ZnO) (Mohammad et al. 2015; Worou et al. 2021a, 2021b). In the case of TiO2, NF composite membranes have been prepared recently with a polyethyleneimine (PEI)-NP hybrid active layer through mineralization. Inorganic precursors tetra-n-butyl titanate and tetraethoxysilane were applied, respectively, to prepare PEI-TiO2 and PEI-SiO2 composite membranes (Zhang et al. 2014c). On the other hand, optimized TiO2 NFMs showed a pure water permeability as high as . Molecular layer deposition (MLD) was used as a novel and highly controllable method to prepare TiO2 NFMs with approximately 1 nm pores for water purification. According to Song et al., MLD, as a new TiO2 NFM preparation technique, exhibits great potential to realize excellent control of membrane composition, thickness, and potentially pore sizes in a scalable way (Spijksma et al. 2006; Xia et al. 2007; Song et al. 2016). The ZrO2 was also adopted as an inorganic selective layer in this experiment because it is widely used for its proven high-performance filtration membranes as an inorganic component with superior chemical, physical, and thermal stability, and good hydrophilicity (Ou et al. 2011; Mi et al. 2014). The presence of both (TiO2 and ZrO2) NPs favored an enhancement of the thermal and structural stabilities. As a result of the hybridization and cross-linkage, the membrane performances such as permeation flux and retention rate were improved, as also long-term operating stability. Mohammad et al. demonstrated that hybrid nanomaterials were much better than the normal application of NPs (Mohammad et al. 2015).
The UF membrane of PAN, also known as polyvinyl cyanide or Creslan 61, was hydrolyzed in a sodium hydroxide (NaOH) solution and then immersed into a hydrochloric acid solution to prepare its surface to receive a bio-glue with great adhesive strength. In this case, dopamine (DA) hydrochloride, a well-known bio-glue, can be oxidized in an alkaline environment, and it forms a polymer-like coating on various substrates with great adhesive strength. Lv et al. used in their work PEI as a crosslinking component to promote the homogeneous polymerization of DA and uniform co-deposition of PDA-PEI (Lv et al. 2016). To avoid this self-aggregation of DA and to obtain a smooth and dense selective layer, DA hydrochloride was dissolved in Tris–HCl buffer solution. Thus, three different TFC membranes, TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon, have been prepared, respectively, with TiO2, zirconia (ZrO2), and both (TiO2, ZrO2) as the inorganic selective top layer.
Materials and agents
The UF membrane of PAN, also known as polyvinyl cyanide or Creslan 61 flat-sheet , with a-, and a pore size of , is a commercial product of Jiangsu Kaimi Membrane Technology Co. Ltd (China) or is available in Shanghai Mega Vision Membrane Engineering & Technology Co. Ltd (China). DA hydrochloride and Tris buffer solution were purchased from Aladdin (China). Titanium sulfate hydrate (Ti·SO4·H2O), hydrochloric acid solution (12 mol/L), zirconium sulfate tetrahydrate (Zr (SO4)2·4H2O), ethanol, and NaOH were all obtained from Sino Pharm Chemical Reagent Co., Ltd and used as received., , , and were supplied by Aladdin (China).
Steps of TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon preparation
Fabrication of hydrolyzed PAN UF membrane and DA/TRIS-coated hydrolyzed PAN UF membrane
The PAN UF membrane (UFM) has been hydrolyzed in NaOH solution (1.5 mol/L) for 1 h 30 min at 50 °C and then immersed into hydrochloric acid solution (2 mol/L) for another 1 h 30 at 30 °C. The resulted membrane is called H-UFM, hydrolyzed PAN UFM, as shown in Figure 1.
DA hydrochloride was dissolved in Tris–HCl buffer solution (pH = 8.4; 55 mmol/L) to prepare another solution used later for deposition with a total concentration of 1.9 g/L, and the deposition time was set at 2 h. These conditions are based on the mass of DA HCl–Tris buffer solution deposited on the membrane surface and the thickness of the coating layer. The circular pieces of UFM with a diameter of 61 mm were pre-wetted by ethanol for 30 min and then transferred into the freshly prepared DA HCl–Tris buffer solution (DA–TRIS) and shaken at 30 °C for 2 h. The synthesized platforms (DA—TRIS-coated H-UFMs) were washed by deionized (DI) water and dried in an ambient environment (Figure 1).
Organic–inorganic TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon synthesis
Finally, solutions of Ti·SO4·H2O and Zr (SO4)2·4H2O were prepared.
Solution 1: Ti·SO4·H2O was dissolved in a hydrochloric solution (45 mmol/L) with a concentration of 5 mmol/L.
Solution 2: Zr (SO4)2·4H2O was dissolved in a hydrochloric solution (45 mmol/L) with a concentration of 5 mmol/L.
Solution 3: Both solutions 1 and 2 were used separately for deposition.
Subsequently, some pieces of DA–TRIS-coated platform membranes were immersed in solution 1 at room temperature (30 °C) for 12 h. These membranes were rinsed several times and dried in a vacuum oven overnight. The resulted membrane, in this case, is called TFC-NFTitan. The preparation process is schematically presented in Figure 2.
Other pieces of DA–TRIS-coated PAN membranes were immersed in solution 2 at room temperature (30 °C) for 12 h. These membranes were also rinsed several times and dried in a vacuum oven overnight. The resulted membrane is called TFC-NFZircon. The preparation process is schematically presented in Figure 2.
The final pieces of DA–TRIS-coated HPES membranes were immersed into solution 1 at room temperature (30 °C) for 6 h and then transferred into solution 2 under the same conditions (temperature, T = 30 °C; hour, t = 6 h). The resulted membrane is called TFC-NFTitanZircon, and the preparation process is schematically presented in Figure 2.
Field emission scanning electron microscopy
Field emission scanning electron microscopy (FESEM) was used for DA—TRIS-coated platform, TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes' surface morphology investigation, and the results were written down and interpreted (Figure 4).
The elements observed on the membrane's surface were carbon (C), oxygen (O), nitrogen (N), titanium (Ti), and zirconium (Zr). Each element of an energy-dispersive spectrometer (EDS) has its X-ray characteristic wavelength. The size of the characteristic wavelength depends on the characteristic energy ΔE released during the energy-level transition. The energy spectrometer uses X rays of different elements. The characteristics of photon characteristic energy are different for component analysis.
Atomic force microscopy
An atomic force microscopy (AFM, MultiMode Vecco, USA) is used to observe the morphology and roughness of the membranes in a tapping mode using silicon tips with nanometer-scale resolution in air. Four membranes' roughness has been measured and reported in this work, DA—TRIS-coated Platform, TFC-NFTitan, TFC-NFZircon, and TFC-TitanZircon.
Water contact angle
Dynamic water contact angle (WCA) measurements were performed with an EasyDrop Instrument (DropMeter A-200 contact angle system; MAIST Vision Inspection & Measurement Co. Ltd, China) at room temperature using the drop method, in which a drop of water was deposited on the surface of a piece of the membrane using a micropipette. The contact angles were measured automatically by a video camera in the instrument using drop shape analysis software. Several measurements on each membrane piece were performed. Five membrane pieces were immersed in ethanol for 30 min and dried in an oven before measuring their contact angle (Figure 5(a)).
The electrokinetic analyzer (SurPASS Anton Paar, GmbH, Austria) has been used to detect the charging property of the membranes' surface. Five samples have had their zeta potential measured: H-UFMs, DA—TRIS-coated platform, TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon, as made clear in Figure 5(b).
Stability test in various solvents
Immersion tests were carried out with each membrane to determine their long-stability in solvents for a 120 h test at room temperature. Every 12 h, both water flux and rejection were measured for each novel organic–inorganic TFC-NF membrane. The membranes withdrawn after this period were carefully rinsed with water and dried at atmospheric conditions.
Membrane performance evaluation
RESULTS AND DISCUSSION
TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membrane characterization
To provide important insights into the arrangement and potential functions of NP layer-coated substrates, a scanning electron microscope (SEM) has been combined with an EDS. In Figure 3, the results of energy spectrum analysis for the TFC-NFTitanZircon membrane are reported. The EDS identified five elements such as C, O, N, Ti, and Zr due to its unique X-ray signals. It is, therefore, possible to characterize and modify the materials at the atomic scale, providing unparalleled insight into the behavior of nanomaterials and particles (Supplementary Material, Figures S1 and S2). In Figure 3, the individual atomic positions can be distinguished by their unambiguous chemical signal. The individual atomic columns are not only visible but also distinct from their neighbors due to their high contrast. In Supplementary Material, Figures S1 and S2, the results of energy spectrum analysis for TFC-NFTitan and TFC-NFZircon, respectively, are reported.
Figure 4 shows surface roughness, morphology, and elements repartition for DA–TRIS-coated Platform (P), TFC-Titan (M1), TFC-Zircon (M2), and TFC-TitanZircon (M3). These characteristics are of great importance in NF. Membrane (P) is the roughest (Ra = 28.9 nm) according to the AFM image (Figure 4(a)), which the SEM (Figure 4(b)) seems to confirm. The membrane surface has changed significantly with the formation of the TiO2 top layer in Figure 4(d) and 4(e). The roughness decreased significantly from 28.9 to 8.02 nm (Figure 4(f)). The remarkable difference between membrane P and membranes M1, M2, and M3 is due to the fact that P is a UF substrate, while the others are NF membranes. A dense and smooth selective layer like in the case of TFC-NFTitanZircon (M3) is beneficial for outstanding TFC-NFMs in general. It was demonstrated further in the forthcoming paragraph that M3 provides the highest rejection performance in comparison with M1 and M2.
The WCA was used to evaluate the wettability of the H-UFM, DA–TRIS-coated platform (P), TFC-NFTitan (M1), TFC-NFZircon (M2), and TFC-NFTitanZircon (M3) (Figure 5(a)). The H-UFM shows the best hydrophilicity due to its hydrophilic groups combining with the porous structure which are covered later by DA–TRIS coating. As the top layer becomes more and more smooth and dense, an increase in WCA results. This phenomenon is further enhanced after the NPs’ TiO2 and ZrO2 layers were fabricated on the mussel-inspired platform surface, which is ascribed to the more dense and smooth structures for the three novel fabricated membranes. Although the novel TFC NFM is the least hydrophilic of all the membranes investigated, it still exhibits good hydrophilicity and can, therefore, be fast spread out by water, which is good for their permeation performance (Somvanshi et al. 2020). On the other hand, Donnan's potential at the interphase of solution and membrane excludes co-ions from the NFM (Sanchez et al. 2005; Luo & Wan 2013). Thus, the surface charge plays a crucial role in organic–inorganic TFC NFM preparation.
Figure 5(b) demonstrates the zeta potentials of the studied membranes at various pH values. At all pH values, the H-UFM exhibits the lowest zeta potential in comparison with the other membranes. The electronegativity (−70 mV) of H-UFM when pH is between 6 and 8.5 is favorable for the co-deposition of DA–TRIS. As observed in Figure 5(b), zeta potential decreases dramatically for the DA–TRIS-coated platform, which is mainly due to the introduction of abundant amino groups from the tris buffer. The potential reduces slightly for TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon after introducing the NP layers on the platform surface, as the electro-positivity of the TiO2 and ZrO2 NPs is slightly more than that of the DA–TRIS coating (Lv et al. 2016). These results demonstrate that the novel prepared organic–inorganic TFC-NFMs are positively charged during the NF process conducted at pH 6.0.
Permeability of TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes
The three different TFC membranes, TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon, have been prepared, respectively, with TiO2, ZrO2, and both (TiO2 and ZrO2) as the inorganic selective top layer by the controlled hydrolysis process of Ti·SO4·H2O and Zr (SO4)2·4H2O. The equilibrium reactions that occur are as follows:
NFMs are usually applied to separate ions with different valences from water and the retention performance of salts can also reflect the charge characteristics of membranes (Farooq et al. 2020; Tofighy & Mohammadi 2020; Yang et al. 2020b; Zhao et al. 2021). Thus, in this section, various salt solutions were used to evaluate the rejection performance of the three novel organic–inorganic TFC-NFMs. The water flux and salt rejection of TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes with , , , and are shown in Figure 6. The rejection ratio reaches as high as 94% for bivalent cations, although it is lower than 30% for monovalent cations. The order of salt rejection of TFC-NFTitan is , as exhibited in Figure 6(a), whereas those of TFC-NFZircon and TFC-NFTitanZircon are, respectively, and CaCl2 > in Figure 6(b) and 6(c). These results are reasonable in those NF processes mainly determined by Donnan and dielectric effects (Wang et al. 2012). TFC-NFTitanZircon exhibits the highest rejection toward both divalent cations (between 89 and 95%) and monovalent cations. The novel organic–inorganic TFC-NFMs are positively charged at pH 6.0 and hence possess a better rejection of multivalent cations than anions (Figure 5(b)). The water flux value for each salt is quite similar under the three novel membranes and is set at , respectively, for TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon. Figure 6(d) depicts the water flux and salt rejection of DA–TRIS-coated platform membrane with an extremely high flux but poor salt rejection.
The synthesized NF membranes’ (TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon) water flux and rejection performance are reported in Table 1, together with those of some earlier reported ones.
|Membranes .||Water flux (L·m−2·h−1) .||Rejection (%) .||References .|
|60||>90||Lv et al. (2016)|
|4.2||81.9||Vatanpour et al. (2012)|
|24||80||Vatanpour et al. (2014)|
|Membranes .||Water flux (L·m−2·h−1) .||Rejection (%) .||References .|
|60||>90||Lv et al. (2016)|
|4.2||81.9||Vatanpour et al. (2012)|
|24||80||Vatanpour et al. (2014)|
TFC-NFTitanZircon is the best performing of the three membranes synthesized in this study. Thus, it can be deduced that the co-deposition of NPs seems to promote the performance of NF membranes. Also, this point of view is widely shared by Polyakov et al. in their recent work on direct co-deposition of nano-sized NPs (Polyakov et al. 2020) and Cui et al. on Mussel-Inspired co-deposition of DA/SiO2 NPs (Cui et al. 2020).
Generally, synthesized NF membranes are either efficient at rejecting ions or display high flux permeate release (Table 1); if the scientific world studies NPs, their affinity, and the stoichiometric conditions of their co-deposition, it could be very beneficial for the development of a next high-performance generation of NF membranes.
Effects of operating conditions on the permeability of TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon
Thermal stability of novel organic–inorganic TFC-NFMs
The effect of operating temperature on these membranes is shown in Figure 7(a), under the operating pressure of 0.6 MPa. It was observed that the water flux of all novel organic–inorganic TFC-NFMs increased quickly about two times between 10 and 30 °C and just about one time between 30 and 60 °C. Since it is not very comfortable to carry out these operations at very high temperatures when it comes to large-scale production, the operating temperature has been set at 30 °C. This increase in water flux was mainly due to the diffusion coefficients, which increased, while the viscosity coefficients of water solution decreased with the increase in temperature (Athar et al. 2020; Kondoh et al. 2020; Nazir et al. 2020; Pavon et al. 2020). The quite constant rejection of the TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes, even when the operating temperature reached 60 °C, partly demonstrated the good thermal stability of the novel organic–inorganic TFC-NFMs. Therefore, it is possible to enhance the water flux by increasing the operating pressure (Figure 7(d)) and temperature with constant salt rejection.
Hydrolyze time effect on novel organic–inorganic TFC-NFMs
The efficacity of the novel organic–inorganic TFC-NFMs was evaluated with a cross-flow NF process. The NP layers are formed by controlling the hydrolysis of Ti·SO4·H2O and Zr(SO4)2·4H2O according to Equations (1)–(5). Therefore, the performance of TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon will be influenced by the hydrolysis parameters such as hydrolysis time and acid chloride concentration. In Figure 7(b), both a dramatic decrease in water flux and a dramatic increase of saltrejection were noticed at the beginning of the experiment (the first 3 h). This state of affairs is understandable and is due to the change in the nature of the membranes from a UF membrane to a NF membrane. For membranes TFC-NFTitan and TFC-NFTitanZircon, the salt rejection peak was reached around 9 h but changed not till 12 h, whereas it was necessary to wait until 12 h before reaching the rejection peak with the TFC-NFTitanZircon membrane. However, both the water flux and the rejection changed little as the hydrolysis time extended to 24 h. Therefore, 12 h was chosen as the optimal hydrolysis time considering both the water flux and rejection performance of the three novel organic–inorganic TFC-NFMs.
Effect of HCl concentration on novel organic–inorganic TFC-NFMs
Figure 7(c) exhibits the effect of HCl concentration on novel fabricated NFMs. According to Equations (1)–(5) relative to the hydrolysis mechanism of Ti2+ and Zr2+ in water, it was indicated that low pH will reduce the reaction rate in the titanium sulfate and zirconium sulfate solutions, respectively, and resulted in TiO2 and ZrO2 NPs on the DA–TRIS-coated membranes surface. For TFC-NFTitan and TFC-NFZircon, both water flux and rejection increase with HCl concentration in the range of 0–45 mmol/L. But, from 45 to 60 mmol/L, the rejection increased slightly and decreased in the same order for each of them, respectively. For membrane TFC-NFTitanZircon, the water flux increased with HCl concentration; the rejection increased, while the HCl concentration increased from 0 to 30 mmol/L and remained constant between 30 and 60 mmol/L. Thus, it is very easy to find the optimal concentration of HCl for the three membranes. A concentration of 45 mmol/L satisfied the performance of these membranes toward both rejection and high-water flux.
Figure 7(d) shows the effect of operating pressure on water flux and rejection of the novel prepared NFMs while the operating temperature was set at 30 °C. It was observed that the water flux of the TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes nearly increased linearly, respectively, from 20 to 51 L·m−2·h−1, 21 to 59 L·m−2·h−1, and 12 to 56 L·m−2·h−1 as the operating pressure increased from 0.2 to 0.6 MPa. Thus, the water flux increased with the operating pressure as predicted by the Spiegler–Kedem Model (Spiegler & Kedem 1966). On the other hand, the rejection rates increased very slightly by 13, 10.5, and 9.1%, respectively, for membranes TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon.
Long-term stability test on novel organic–inorganic TFC-NFMs fabricated
To evaluate the long-term stability of the TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon membranes, a continuous filtration test of 120 h was carried out on each membrane. The results are presented in Figure 8. For test conditions, the salt solutions used are, respectively, , since TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon exhibited the best performance rejection toward the latter ones (concentration [1,500 mg/L], 30 °C, pH = 6.0, 0.6 MPa, and cross-flow rate = 30 L/h). Globally, for all the three membranes, both the water flux and the rejection exhibited satisfying long-term stability. The water flux of the TFC-NFTitan membrane (although the lowest) remains quite constant over time for a decrease of less than 2%. The water flux for both TFC-NFZircon and TFC-NFTitanZircon membranes, from the beginning to the end of the long-term operation, varied very slightly and remained high (more than 50 L·m−2·h−1) till the end of the test. During the 120 h test, all three membranes performed very well at the nearly constant rejection rates of 93, 80, and 68%, respectively, for membranes TFC-NFTitan, TFC-NFZircon, and TFC-NFTitanZircon. The good durability of these membranes is closely related to the interfacial compatibility between the NPs (TiO2 and ZrO2) as selective layers and the support surface UF membrane through the robust and multiple binding forces between DA–TRIS-coating H-UFM. The high rate of rejection and the low water flow rate of the TFC-NFTitan membrane are certainly due to the greater fineness of the TiO2 NPs compared with that of the ZrO2 NPs. Thus, this test made it possible to demonstrate the long-term effectiveness of the novel TFC-NFMs prepared in this work.
Three new organic–inorganic TFC-NF membranes were manufactured by the in situ formation approach formed with Ti, Zr, and a co-deposition of these two NPs. The three novel membranes under the optimized preparation conditions (30 °C, 12 h of hydrolysis time, , and operating pressure of 0.6 MPa) exhibited high rejection and permeation performance. All three membranes demonstrated long-term durability under a 120-h testing. TFC-NFTitanZircon obtained by the co-deposition of both NPs showed the highest rejection (89–95%) for divalent cations with the salt rejection sequence of , while the water flux is not less than . We strongly recommend that the scientific world begin to study much more in the future on how to combine two or more NPs according to their affinity, leading to more efficient and more robust membranes.
The authors would like to thank our group members for their kind help and suggestions.
CONFLICT OF INTEREST
The authors declare no competing financial interest.
DATA AVAILABILITY STATEMENT
All relevant data are included in the paper or its Supplementary Information.