Most of the open well water is of low pH and polluted by an excess of turbidity, acidity, and iron in the district of Malappuram, Kerala, India. In this work, water samples were collected in a random manner from 15 blocks of Malappuram in between the post- and pre-monsoon seasons and their quality was studied using standard analytical procedures. Based on the experimental analysis, various physicochemical characteristics, namely turbidity, temperature, pH, total dissolved solids, total alkalinity, and iron have been evaluated. It is found that all samples under investigation were of low pH and some samples were contaminated by turbidity, acidity, and iron. However, total dissolved solids and total alkalinity are within the desirable limit in all samples. Samples having excess turbidity and iron show a reddish brown color that causes coloration and stain to sanitary fittings, clothes, etc. Excess iron also give an unpalatable metallic taste to the drinking water.

  • Water quality assessment of open wells in Malappuram district.

  • Various water quality parameters are determined.

  • The well water has a low pH.

  • TDS and total alkalinity are within the desirable limit.

Graphical Abstract

Graphical Abstract
Graphical Abstract

Water is one of the most precious commodities in this world. Although two-thirds of Earth's surface is covered by water, only a small amount of water can be effectively utilized for human needs. Surface sources contribute about one third of the drinking water requirements of the world. Unfortunately, this small amount of potable water is also deteriorating day by day due to anthropogenic activities. The problem has been intensified in the last few decades and the situation is alarming in most places.

Kerala is known as God's own country because of its abundant natural resources, mainly water. The state usually receives a tremendous amount of rain water, about 2,800–3,200 mm of rain every year. There are 44 rivers and 34 backwaters; mostly in the form of lakes and ocean inlets and others are fresh water lakes. Besides this, the state is blessed with numerous streams, about 18,600 ponds and over 70 lakhs dug wells. Kerala is one of the most dug well density areas in the world (Harikumar & Kokkal 2009; Geethu Krishna et al. 2014).

In the modern world, water pollution is one of the most serious problems. Like most of the other types of pollution, water pollution is also associated with human activities. Human and animal feces, seepage from pit latrines and septic tanks, household waste, refuge dumps, industrial, domestic, and all municipal wastes released into water bodies, agricultural runoff, landfills debris from, construction sites, etc. are some of the important causes of water pollution. Pollutants may be decaying and miscible with soil and waterbodies. An obvious and asymptomatic issue with the pollutants is their effect on water quality. Decomposition of the above pollutants may result in the production of compounds like carbon dioxide, water, simple organic compounds like methane, simple fatty acids, etc. (Dlugokencky et al. 2003). These substances may be miscible with rain water, oozing through the soil and reaching the ground water as well as deep ground water which causes the contamination of ground water sources, too.

Most of the land area in Malappuram is thickly populated and hence the place has a high pollution rate where water is one of the most evident victims of pollution. In Kerala, the southernmost state of India, most of the people depend on the open wells or shallow wells and each house has at least one well. The sources are most often surrounded by so many pits like soak pits, leach pits, pit latrines, septic tanks, etc. As the contaminated water may be leaching from the pits, these pits increase the chances of contamination.

In the rainy season, there is an excess quantity of water in all sources and hence less chemical quality problems are found. Although the Bureau of Indian Standards (BIS) has fixed the quality standards for drinking water, most of the drinking water sources are below the standards due to excess pollution (Bureau of Indian Standards 2012). In this regard, the present work aimed at assessing various water quality parameters of open wells in Malappuram district, Kerala. The study was carried out in the month of January 2022 which is in between the post-monsoon and pre-monsoon seasons in Kerala.

For the analysis, analytical grade chemicals and doubly distilled water were used. The water quality parameters were analyzed as per American Public Health Association (APHA) (APHA 2005) and the quality parameters were followed as per BIS 10500:2012 (Bureau of Indian Standards 2012). The instruments such as a thermometer, portable pH meter, nephelo turbidity meter, and UV-visible spectrophotometer were used in the analysis. Forty-five samples from open wells were collected randomly from 15 blocks (three samples from each block) in the Malappuram district. Samples were collected in a clean and fresh 1 L plastic cane. The physical parameters like temperature and pH were analyzed at the time of sampling itself whereas turbidity total dissolved solids (TDS), acidity, total alkalinity, and iron were analyzed in the water testing laboratory.

High temperature leads to the growth of microorganisms in water sources (Shaji et al. 2009). The low, high, and average values of various physicochemical parameters of the 45 well water samples along with the permissible value as per Indian Standard 10500:2012 are listed in Table 1. The ambient temperature at the time of sampling was in the range of 28.1–34.6 °C and an average of 31.3 °C. A plot of temperature against different water samples collected from the open wells of Malappuram district, Kerala is shown in Figure 1.
Table 1

The low, high, and average values of various physicochemical parameters of the analysed water samples

ParameterValue
Permissible limita
LowHighAverage
Temperature (°C) 28.10 34.60 31.30 – 
Turbidity (NTU) 0.20 14.90 3.59 
pH 5.08 6.54 5.97 6.5–8.5 
Total dissolved solids (mg/L) 52.90 178.50 99.41 500 
Total alkalinity (mg/L) 21.90 75.92 48.40 600 
Iron (mg/L) 0.01 2.21 0.55 1.0 
ParameterValue
Permissible limita
LowHighAverage
Temperature (°C) 28.10 34.60 31.30 – 
Turbidity (NTU) 0.20 14.90 3.59 
pH 5.08 6.54 5.97 6.5–8.5 
Total dissolved solids (mg/L) 52.90 178.50 99.41 500 
Total alkalinity (mg/L) 21.90 75.92 48.40 600 
Iron (mg/L) 0.01 2.21 0.55 1.0 

Note: The uncertainty in temperature, turbidity, pH, total dissolved solids, total alkalinity, and iron were ±0.37, ±0.07, ±0.05, ±4.99, ±0.86, and 0.03, respectively.

aAs per Indian Standard 10500:2012 (Bureau of Indian Standards 2012).

Figure 1

Plot of temperature versus sample numbers of collected water samples from open wells of Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 1

Plot of temperature versus sample numbers of collected water samples from open wells of Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal
One of the problems normally found in waterbodies in Kerala is the turbidity. The heavy rain in the monsoon season causes erosion and so the water is mixed well with soil, clay, and other suspended particles. This always increases the turbidity of surface water. Iron, algae, and other suspended particles may also contribute to turbidity contamination in the summer season. The turbidity imparts an unpalatable appearance and it decreases the rate of disinfection (World Health Organization 2017). The plot of turbidity against different water samples collected from the open wells of the Malappuram district, Kerala is exposed in Figure 2. It can be seen that 17 samples of water, collected from the open wells of the Malappuram district, show a turbidity value within the desirable limit of 1 NTU. The turbidity of 11 samples exceeded the permissible limit of 5 NTU whereas the remaining samples had turbidity above the desirable but below the permissible limit (that is in between 1 and 5 NTU). The average value of turbidity is found to be 3.59. The main reason for high turbidity is the presence of iron contamination as well as suspended pollutants.
Figure 2

Plot of turbidity versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 2

Plot of turbidity versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal
According to the World Health Organization (WHO), pH has no direct impact on human health. However, a very low pH can cause taste changes, usually a sour taste to drinking water. Low pH is one of the major causes of corrosion, wherever the water is in contact. Moreover, acidic water may leach the metals (lead, manganese, copper, iron, etc.) present in the soil and also from the distribution pipes. In such circumstances, the water becomes toxic for human beings depending on the concentration of leached metals. Furthermore, a high pH (above 8.5) makes water bitter in taste and a very high pH may cause itching, dryness, and irritating feelings on the eyes and skin. Results show that low pH is one of the significant problems found in the open well sources in the Malappuram district. This can be due to the presence of dissolved carbon dioxide in water. As per BIS 10500:2012, most of the wells are characterized by low pH values. The pH of the studied water samples ranged from 5.08 to 6.54 as shown in Figure 3. The average pH value is found to be 5.97 and is lower than that of the recommended limit of 6.5. The increase in acidity can cause many adverse biological effects (WHO n.d.). None of the samples in the present work showed a pH value above 6.5.
Figure 3

Plot of pH versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 3

Plot of pH versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal
Normally, the presence of dissolved solids in open wells is comparatively low and does not exceed the limit. The plot of TDS with studied water samples collected from the open wells of Malappuram district, Kerala is depicted in Figure 4. The study shows that all the well waters have low TDS which do not exceed the limit of 500 mg/L. The maximum TDS obtained is found to be 178.5 mg/L and the average value of TDS was 99.41 mg/L.
Figure 4

Plot of total dissolved solids versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 4

Plot of total dissolved solids versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal
Figure 5 depicts the variation of total alkalinity against the sample numbers of collected water samples of open wells in Malappuram district, Kerala. It can be seen that the total alkalinity present in all of the samples is below the desirable limit of 200 mg/L. The results suggest the absence of hardness and the contaminants like chloride, calcium, and magnesium.
Figure 5

Plot of total alkalinity versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 5

Plot of total alkalinity versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal
Iron contamination in drinking water is an important water quality problem. In addition to an increase in turbidity, it imparts an unpalatable metallic taste, stains on utensils, clothes, tiles, closets, etc., and an oily appearance on the surface of water sources due to the presence of iron bacteria. The plot of the amount of iron against sample numbers of collected water samples from open wells of Malappuram district, Kerala is shown in Figure 6. Out of the 45 samples tested, 10 samples are found to have excess iron. The desirable limit and permissible limit of iron in drinking water is 1.0 mg/L. The lowest and highest values of iron content in the studied water samples are 0.01 and 2.21 mg/L, respectively. The average quantity of iron content present in the water samples was 0.55 mg/L.
Figure 6

Plot of amount of iron versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Figure 6

Plot of amount of iron versus sample numbers of collected water samples from Malappuram district, Kerala. Line drawn to guide the eyes only.

Close modal

To analyse the water quality, samples were collected from open wells of 15 blocks in Malappuram district, Kerala, India, during the period between post- and pre-monsoon seasons. The study reveals that all the 45 samples have low pH and the water in these open wells is slightly acidic. The turbidity of 13 samples is found to exceed the permissible limit. Dissolved solids and total alkalinity in all the samples are within the desirable limit. The hardness and presence of chloride are very low in the open well water samples of the Malappuram district. As nine samples show excess iron contamination, these samples are not fit for drinking purposes as per BIS and hence proper treatment methods should be adopted before the use of this water.

All relevant data are included in the paper.

The authors declare there is no conflict.

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