Abstract
Understanding the transport of point source solutes across the sediment–water interface (SWI) is important for the protection of river environments. Conventional coupled models assume the porous media layer as Darcy's laminar flow and therefore cannot accurately capture the transport processes within the porous media. Furthermore, the effect of the porous structure of the riverbed on the transport process is largely unknown. In this study, we performed pore-scale numerical simulations of point source solutes transport across the SWI to investigate the effects of different porous structures in the riverbed on flow and point source dispersion. By solving the Reynolds-averaged Navier–Stokes equations with the k–ω shear stress transport turbulence closure model, we determine the complex flow field information and the spatial distribution of point source solutes for the coupled model. The results indicate that the presence of porous structures creates recirculation zones in the coupled model, which prevents turbulent structures reaching deeper layers. Random porous structures induce more preferential flow, inhibit the formation of recirculation zones, and exhibit higher solute dispersion, which is directly related to turbulent solute fluxes. Furthermore, our study reveals that the release position of point sources significantly influences the distribution of solute concentrations within the porous bed.
HIGHLIGHTS
The influence of porous structures on flow and point source dispersion is elucidated within a coupled system of overlying water and porous media.
Random porous structures will induce more preferential flow and accelerate solute transport.
The presence of preferential flow inhibits the formation of recirculation zones.
Turbulent solute flux explains the wider distribution of random porous structures.
INTRODUCTION
For the coupling model of overlying water and porous media, the conventional models usually represent the porous media layer as Darcy's laminar flow, which has been proven to simulate solute transport in fine-grained riverbeds (Cardenas & Wilson 2007a; Janssen et al. 2012; Hester et al. 2019). However, this approach has limitations in modelling solute exchange processes in coarse-grained riverbeds and usually underestimates the exchange flux across the SWI. This is mainly because the extended turbulence into the transition layer, commonly ignored in conventional models, significantly contributes to solute exchange processes near the SWI and accelerating solute transport from the overlying water into the porous medium (Reidenbach et al. 2010; Han et al. 2018; Lian et al. 2019; Roche et al. 2018). Moreover, this modelling approach also underestimates the inertial effects of complex pore scales in porous media layers, which includes preferential flow and recirculation zones for interfacial solute exchange (Bottero et al. 2013; Zhou et al. 2019; Kim et al. 2023). The interfacial mass flux induced by overlying water turbulence is six times higher in coarse-grained riverbeds than in fine-grained riverbeds, as demonstrated by Reidenbach et al. (2010). Therefore, the assumption of a porous media layer as Darcy's laminar flow is not suitable in modelling coarse-grained riverbeds, and it may significantly underestimate the interfacial mass exchange flux.
Recent studies based on direct measurements indicate that the turbulence of the overlying water directly affects the flow characteristics within the porous media layer and that a recirculation zone is formed in the porous space near the SWI, which may serve as a temporary storage area for solutes that can be subsequently re-released into the overlying water (Blois et al.2012; Bolster et al. 2014; Roche et al. 2018). This anomalous solute transport characteristic deviates from Fick's law (Crevacore et al. 2016; Kim et al. 2020). Therefore, we need to clarify the solute transport properties within the porous structure to better understand the non-Fickian characteristics of the solute transport process.
Furthermore, several studies on coupled modelling of overlying water and porous media at the pore scale usually idealise the porous media layer as regularly arranged circular or square particles (Prinos et al. 2003; Fang et al. 2018; Lian et al. 2019; Kim et al. 2020; Cho et al. 2022; Singh et al. 2022). To the best of our knowledge, only a limited number of studies have explored the effects of irregular distributions. These investigations have revealed that the arrangement of porous structures not only influences the flow of pore water but also has a significant impact on the overall flow pattern of the coupled model (Bartzke et al. 2014; Suga et al. 2020; Shen et al. 2021; Kim et al. 2023). Random porous structures produce distinct stagnation zones and preferential flows, which directly affect the solute transport process across the SWI; therefore, a more comprehensive understanding of the effect of porous structures on flow transport patterns is necessary.
In nature, the sources of solute pollution in overlying water are mainly from the discharge of industrial wastewater and domestic sewage, and such inputs from specific pollution sources are collectively referred to as point sources (Pal et al. 2010; Li 2014). Point source pollution of rivers may include chemicals, organics, heavy metals, nutrients, and so on, which may have direct impacts on water ecosystems (Wilhelm 2009; Hou et al. 2021). However, although riverine point source pollution is a common mode of solute diffusion, the exact mechanism of its diffusion at the pore scale is unknown.
In this study, we developed a pore-scale coupled model of overlying water and porous media, and further evaluated the effects of regular and random porous structures on the flow characteristics and point source dispersion characteristics of the coupled model. To achieve this, we utilise a 2D k–ω shear stress transport (SST) turbulence model to accurately resolve the flow characteristics of the coupled pore-scale model. Once the flow field is sufficiently developed, we release a point source consisting of non-reactive solutes at the SWI to analyse and obtain the spatial distribution characteristics of solute transport for the coupled model. Then, the effect of Reynolds numbers on the coupled model flow and dispersive transport of the point source is further explored. Furthermore, the turbulent solute flux is utilised to establish the relationship between interfacial turbulence and solute diffusion. In addition, we explore the variability of different release positions of the point source to gain further insights into the dispersion process.
METHODS
Hydrodynamic model
To accurately capture the segregated flow in the complex structure of porous media, we analyse the hydrodynamic properties of a coupled model of overlying water and porous media using the Reynolds-averaged Navier–Stokes equations with the k–ω SST turbulence closure model. The model combines the advantages of both the k–ε and the k–ω turbulence models to better handle adverse pressure gradients and flow separation, which is particularly effective in predicting the behaviour of boundary layers and turbulent flows with complex vortex structures near walls (Menter 1994; Menter et al. 2003; Lee et al. 2021; Sarmiento-Laurel et al. 2022).
The closure coefficients , , , , and are 5/9, 3/40, 9/100, 1/2, and 1/2, respectively (Menter 1993).
Non-reactive solute transport model
In this study, the point source consists of non-reactive solutes, and only the effect of hydrodynamic processes on solute migration and diffusion is considered, without taking into account the reactive transport processes of solutes, which is the same as in previous studies (Tanino & Nepf 2008; Jin et al. 2010; Guo et al. 2022).
Setup of numerical experiments
Model validation cases
Parameter . | Description . | Value . |
---|---|---|
(m) | Overlying water depth | 0.03 |
(m) | Porous layer depth | 0.055 |
Porosity | 0.8286 | |
(m/s) | Shear velocity | 0.0243 |
Reynolds number | 7.581 × 103 | |
(m2) | Permeability | 4.107 × 10−4 |
Parameter . | Description . | Value . |
---|---|---|
(m) | Overlying water depth | 0.03 |
(m) | Porous layer depth | 0.055 |
Porosity | 0.8286 | |
(m/s) | Shear velocity | 0.0243 |
Reynolds number | 7.581 × 103 | |
(m2) | Permeability | 4.107 × 10−4 |
Based on these experiment parameters, Prinos et al. (2003) conducted numerical simulations using the 2D RANS equations based on the standard k–ε turbulence model. Furthermore, we compared the model results with the numerical simulation results of Kim et al. (2020) using the renormalization group (RNG) k–ε turbulence model to demonstrate the advantages of the k–ω SST turbulence model in dealing with flow in complex porous media.
First, we created a 100 × 100 square computational domain with dx and dy of 1. The point source is released at position (50, 50). In this study, D and u were set to 0.001 and 0.01, respectively.
Study cases
When the turbulence is sufficiently developed, we applied a point source at position , to assess the dispersion of the point source at the SWI. The simulation parameters are summarised in Table 2. In the case name, Regular002, Regular010, Random002, and Random010 represent two regular porous structure cases and two random porous structure cases, respectively. Note that 002 and 010 denote inlet velocities = 0.02 and 0.10 m/s, respectively.
Parameter . | Description . | Regular002 . | Regular010 . | Random002 . | Random010 . |
---|---|---|---|---|---|
(m) | Overlying water depth | 0.0325 | 0.0325 | 0.0325 | 0.0325 |
(m) | Porous layer depth | 0.0675 | 0.0675 | 0.0675 | 0.0675 |
Porosity | 0.636 | 0.636 | 0.636 | 0.636 | |
(m/s) | Inlet velocity | 0.02 | 0.10 | 0.02 | 0.10 |
(m/s) | Mean surface velocity | 0.0427 | 0.2588 | 0.0291 | 0.2033 |
(m/s) | Shear velocity | 0.0033 | 0.0171 | 0.0029 | 0.0145 |
Froude number | 0.07 | 0.46 | 0.05 | 0.36 | |
Reynolds number | 1,388 | 8,411 | 946 | 6,607 |
Parameter . | Description . | Regular002 . | Regular010 . | Random002 . | Random010 . |
---|---|---|---|---|---|
(m) | Overlying water depth | 0.0325 | 0.0325 | 0.0325 | 0.0325 |
(m) | Porous layer depth | 0.0675 | 0.0675 | 0.0675 | 0.0675 |
Porosity | 0.636 | 0.636 | 0.636 | 0.636 | |
(m/s) | Inlet velocity | 0.02 | 0.10 | 0.02 | 0.10 |
(m/s) | Mean surface velocity | 0.0427 | 0.2588 | 0.0291 | 0.2033 |
(m/s) | Shear velocity | 0.0033 | 0.0171 | 0.0029 | 0.0145 |
Froude number | 0.07 | 0.46 | 0.05 | 0.36 | |
Reynolds number | 1,388 | 8,411 | 946 | 6,607 |
Boundary conditions
We apply the rigid lid assumption to the upper boundary when the Froude number , which neglects the fluctuation of the free water surface. This approach is widely used in the application of open channel flows (Van Balen et al. 2010; Janssen et al. 2012; Chen et al. 2018). No-slip boundary conditions are applied to the bottom and the porous structure surfaces. Periodic boundary conditions are implemented in streamwise directions, as illustrated in Figure 2. It is worth noting that since solute migration does not apply to the periodic boundary conditions, to prevent re-entry of the solute from the inlet, we set the scalar value of the inlet close to the release position of the point source to zero and solute migration to a single cycle. The computations were performed on the Hohai High-Performance Computing Center.
RESULTS AND DISCUSSION
Results of model validation
To emphasise the accuracy of the non-reactive solute model in accurately assessing the solute transport process, a test case was carried out and the results are shown in Figure 5. Point source solute is placed and released at the position (50, 50), and a flow field velocity of magnitude of 0.01 m/s is applied in the direction from left to right; the dimensionless solute concentration profiles along the horizontal line y = 50 at time 100 and time 200 are presented. The point source is released at the centre of the simulation region, and over time the solute gradually moves to the right with the flow field due to convective diffusion and spreads throughout the fluid domain. Comparison of the results with the analytical solution gives good agreement, indicating the reasonable validity of the non-reactive solute transport model.
Analysis of hydrodynamic results
Flow field characteristics
At the same porosity, Figure 6(b) shows that the porous structures determine the , where is the mean velocity of the porous domain. The random porous structure will create strong preferential flow path and disrupt the formation of recirculation zones, allowing more water to enter the porous media layer from the overlying water layer, which directly affects the velocity of pore water in the porous media, and the is twice as high as regular porous structures. In other words, exhibits a greater sensitivity towards the pore structure as compared to , and this disparity arises from the fact that the mean velocity structure in the finite water depth is more dependent on the porous structures (Wu & Mirbod 2018; Guo et al. 2020).
Reynolds stresses
To quantify the relationship between the local slope angle and the Reynolds stresses in random porous structures, we define the angle between the first layer and the horizontal line as θ (illustrated in Figure 3(b)). The upstream slopes correspond to θ > 0, while the leeward slopes correspond to θ < 0. In contrast to regular porous structures, where multiple Reynolds normal stress components peak at the SWI, random porous structures exhibit a unique behaviour wherein only the streamwise Reynolds normal stresses peak at the SWI. This is due to the fact that the arrangement of the random porous structures favours the generation of a more stable preferential flow, allowing more overlying water to participate in the water exchange process, which in turn disrupts the formation of the recirculation zone in the porous media layer.
The peak of vertical Reynolds normal stresses and shear stresses exhibit significantly higher values on the upstream slopes compared to the leeward slopes; this is due to the formation of preferential flow, which leads to enhanced vertical exchange of overlying water across the SWI into the porous media layer occurring, and the transient vertical flow velocity is larger. However, the streamwise Reynolds normal stresses on the leeward slopes are higher than those on the upstream slope due to the presence of recirculation zones on the leeward slope, which slows down the streamwise instantaneous velocity in the overlying water; thus, the leeward and upstream slope show differences.
Flow paths and recirculation zones
As a consequence of the swift reduction in turbulence within the overlying water towards the porous layer, solute exchange is predominantly affected in the vicinity of the interface (Figure 4). The recirculation zones and turbulence characteristics near the SWI are considered to be the key factors controlling the mass transfer between the overlying water and the porous layer (Tonina & Buffington 2007; Roche et al. 2018). As shown in Figure 8, the size and location of the recirculation zone strongly depend on the arrangement of the porous structures. More recirculation zones exist in the regular porous structures than in the random porous structures, which are mainly due to the interfacial momentum exchange inherent in the porous space, and the random porous structures will induce a more preferential flow, thus limiting the formation of recirculation zones in the porous media layer. For random porous structures, recirculation zones are mainly found on leeward slopes due to the significantly lower Reynolds stresses compared to upstream slopes and the relatively low flow velocities on leeward slopes, which are favourable for the formation of recirculation zones. Furthermore, in the random porous structures, the existence of preferential flow inhibits the formation of the recirculation zone in the porous media layer, which accelerates the escape of solutes from the recirculation zone, and to some extent reduces the residence time of solutes in the porous layer. The connection between the recirculation zones and solute transport is discussed further in Section 3.3.
Analysis of point source dispersion
Spatial concentration distribution
Turbulent solute flux
The presence of an inverse distribution of turbulent solute fluxes in the porous media layer is due to the shear interaction between the porous structures. For regular porous structures, the peak of the turbulent solute flux is located above the SWI, whereas the peak for random porous structures is closer to the SWI and highly irregular. This is due to the presence of preferential flow in the random porous structures, which weakens the turbulence intensity above the interface, and more water enter the porous media layer, which explains why the solute distribution in the random porous structures is more widespread.
Effects of point release position
In fact, under identical flow conditions, the position of the point source release can greatly influence the distribution of solute concentrations, which is of great significance for environmental applications such as wastewater treatment (Li 2014; Hou et al. 2021). As we delve into the impact of the point source release position in this section, for the sake of brevity, we adopt case002 (Regular002 and Random002) as the reference for point source release at y/H = 0.5 and 1, respectively.
CONCLUSION
In this study, we focus on investigating the significance of randomly distributed porous structures within coupled overlying water and porous media, employing pore-scale numerical simulations. The primary objective is to explore the turbulent characteristics and point source solute transport across the SWI. This research question holds significant implications for the study of fluid flow and transport in coupled systems of surface flow and porous media, spanning various research areas, including procedural water treatment (Wilhelm. 2009; Hou et al. 2021), riverbeds (Blois et al. 2014; Hester et al. 2019), continental shelf sediments (Huettel et al. 2014), porous media (Yang et al. 2014; Wang et al. 2023), and marine particles (Ahmerkamp et al. 2022). In particular, the application in the field of water treatment, which covers the selection of industrial wastewater discharge points and urban domestic sewage discharge points, is of guiding significance for river pollution management.
The hydrodynamic properties of both the overlying water and the porous domain are highly sensitive to the configuration of porous structures. Compared with regular porous structures, random porous structures induce a more preferential flow, prompting a greater influx of overlying water into the porous media layer through the SWI, consequently accelerating the solute transport process. As the Reynolds number increases, the Reynolds stresses exhibit a positive correlation with the flow velocity in the porous domain, resulting in stronger variabilities of the velocity distribution. The peak Reynolds stresses are higher in the case of random porous structures compared to regular ones, favouring a more stable preferential flow pattern and reducing the extent of recirculation zones. The alteration of porous structures significantly influences the flow paths and the formation of recirculation zones. The presence of preferential flow inhibits the formation of recirculation zones, accelerates the escape of solutes from these zones, and reduces the residence time of solutes in the porous layer.
The proximity to the point source release directly affects the solute concentration in the surrounding water column, and convection in the overlying water accelerates the diffusion of solutes. When compared under the same conditions, the random porous structures exhibit higher solute concentrations and have a broader influence compared to regular porous structures. This behaviour can be attributed to preferential flow, which allows solutes to penetrate deeper into the porous layer, peaking at four times the value observed in regular porous structures. The wider distribution of solutes in random porous structures is explained by the turbulent solute flux, where the presence of a shear layer leads to an inverse distribution of longitudinal turbulent solute flux. Furthermore, the position of the point source release substantially influences the distribution of solute concentration, consistently resulting in the peak concentration coinciding with the height of the point source release. Moreover, as the release point approaches the riverbeds, the mixing of solutes accelerate at a faster rate.
In conclusion, this study serves as a logical first step in elucidating the influence of porous structures on flow and point source dispersion within a coupled system of overlying water and porous media. Although this study is based on a mathematical model analysing in detail the flow and point source transport mechanisms in a coupled system of overlying water and porous media, complementary experiments using particle image velocimetry (PIV) and laser-induced fluorescence will further enhance our understanding of such issues. Moving forward, further research and improvements are required in the following areas: (1) conducting experimental studies complementary to numerical modelling; (2) more comprehensive investigation into the link between preferential flow trajectories and the arrangement of pore structures; (3) expansion of the model into a 3D representation to explore spanwise flow and point source dispersion in greater detail; and (4) integration of reactive solutes to better understand the impact on biogeochemical transformation. Addressing these aspects will provide valuable insights and contribute to a deeper understanding of the interactions between porous structures, flow dynamics, and solute dispersion.
ACKNOWLEDGEMENTS
This study was supported by the National Key R&D Program of China (2022YFC3202600), the National Natural Science Foundation of China (52309086), and the Water Conservancy Science and Technology Project in Jiangsu Province (2023013, 2022061). S. A. acknowledges funding by Novo Nordisk Fonden (MATIC) and the Max Planck Society. G. B. was funded through the Cluster of Excellence ‘The Ocean Floor-Earth's Uncharted Interface’, MARUM of the Universität Bremen, Germany.
DATA AVAILABILITY STATEMENT
All relevant data are included in the paper or its Supplementary Information.
CONFLICT OF INTEREST
The authors declare there is no conflict.