Precipitation and catchment characteristics of mountainous headwaters can vary largely within short distances. It remains unclear how these two factors determine the contribution of event water and pre-event water to stormflow. We investigated this in five neighboring headwaters with high annual precipitation amounts (>2,000 mm y−1) in a steep pre-alpine region in Switzerland. Rainfall and streamwater of 13 different rainstorms were sampled (P: 5 mm intervals, Q: 12 to 51 samples per events) to perform a two-component isotope hydrograph separation. Pre-event water contributions based on δ18O or δ2H computation were similar. The pre-event water contributions of headwaters depended largely on rainfall (amount and intensity) and varied more between events than between catchments, despite clear differences in land cover between the catchments. Furthermore, antecedent wetness was not found to control pre-event water contribution. With increasing rainfall amount, the proportion of rainfall in runoff increased and changed from pre-event to event water dominated. The variable rainfall amount and small active storage (organic soil horizon, 20–50 cm) resulted in a threshold in the upper soil horizon with subsequently more variable pre-event water contribution. Our results show the necessity of sampling in different headwaters and events to better understand controlling factors in runoff generation.
INTRODUCTION
Runoff generation processes vary in space and time. The spatial variation is controlled by catchment properties such as land-use/cover and geology, while the temporal variation is mainly controlled by hydrometeorological conditions such as precipitation and soil moisture. Understanding this spatiotemporal variability of runoff processes as a function of precipitation and catchment characteristics is important for predictions of streamflow quantity and quality.
As part of the water itself, the stable isotopes δ18O and δ2H, are valuable conservative tracers in the two end-member mass balance approach (also called two-component isotope hydrograph separation (IHS)) to study how catchments transform rainfall into runoff. Using IHS allows the stormflow hydrograph to be separated, and to discern to what degree rainfall (event water) and water, that has been stored in the catchment before the event (pre-event water), contribute to stormflow (Sklash et al. 1976; Klaus & McDonnell 2013).
IHS has, however, frequently been performed only in single headwaters (e.g., McDonnell et al. 1990; Jordan 1994; Vitvar & Balderer 1997; Renshaw et al. 2003; Pellerin et al. 2008; Lyon et al. 2008; Penna et al. 2014). From several IHS studies in forested headwaters, the general perception developed that pre-event water dominates the peak discharge (Buttle 1994; Klaus & McDonnell 2013). However, the value of an IHS study in one catchment and one event is limited. Such studies are criticized for not providing further insights into hydrological processes (Burns 2002). With advances in laser spectroscopes, measuring the composition of both stable isotopes δ18O and δ2H has become relatively easy and the price per sample has decreased (Lis et al. 2008; Penna et al. 2010). This development has made it possible to investigate more catchments or events. Few early IHS studies compared different catchments (Rodhe 1987) and only recently has IHS been used to compare neighboring headwaters (Onda et al. 2006; Laudon et al. 2007) and/or many events (McGlynn et al. 2004; Lyon et al. 2008; James & Roulet 2009; Roa-García & Weiler 2010; Hrachowitz et al. 2011; Segura et al. 2012). Several of these runoff generation studies found a more variable event and pre-event water contribution, contrary to the presumed dominance in pre-event water found in the single headwater studies. Casper et al. (2003), Pellerin et al. (2008), Kienzler & Naef (2008), James & Roulet (2009), and Penna et al. (2014) could relate an increase of event water to rainfall sum, intensities, and duration (see also Klaus & McDonnell 2013). In forested headwaters, trees not only affect the amount of spatiotemporal throughfall (Gerrits et al. 2010) and isotopic composition (Allen et al. 2015), but also affect the subsurface connectivity (Weiler et al. 1998). Interception and transpiration of trees together with higher infiltration capacities of the soils can have a delaying effect on stream response, and pre-event water dominates the stormflow (Buttle 1994; Roa-García & Weiler 2010; Klaus & McDonnell 2013). Roa-García & Weiler (2010) observed higher pre-event water fractions in wetlands compared to forest and grasslands. Other studies have also observed higher event water fractions in wetlands (McCartney et al. 1998; Laudon et al. 2007) and in grasslands (Bonell et al. 1990). Infiltration capacity, soil type, storage potential of soils (Geris et al. 2015), and macropore distribution (Buttle 1994) are important controlling factors in runoff generation processes. High responsive headwaters with shallow soils of less than a meter have generally limited water storage in the soil mantel (Pearce 1990). Suecker et al. (2000) observed higher event water contributions on steep slopes. In different studies from around the world, described in Buttle (1994) or Jordan (1994), it is difficult to observe a relationship between event water contribution and geology. On the other hand, Onda et al. (2006) however did not observe a significant relation between soil depth and event water, but found that headwaters with ‘permeable’ geologies (larger number of cracks and fissures) had a lower event water contribution.
Brown et al. (1999) and Shanley et al. (2002) observed that event water contribution increases with catchment size, while no relation was found by either McGlynn et al. (2004) or James & Roulet (2009). Seasonality and the state of the system affect flow pathways (Hinton et al. 1994; Penna et al. 2014). Jordan (1994), Casper et al. (2003), and James & Roulet (2009) found that dry antecedent conditions with low connectivity result in higher event water contribution while McGlynn et al. (2004) found the opposite.
Pre-alpine headwaters are characterized by a large spatiotemporal variability of precipitation and variation in land cover, topography, and geology (Gurtz et al. 1999). Despite the heterogeneous catchment characteristics, baseflow processes in neighboring pre-alpine headwaters can be similar (Fischer et al. 2015). During stormflow however, it remains to be quantified how the variability of precipitation and catchment characteristics controls runoff processes in these headwaters.
In this study we investigated a steep pre-alpine region with high annual precipitation amounts (>2,000 mm y−1) in Switzerland using IHS for five neighboring headwaters and 13 different rainstorm events. The objective was: (1) to assess differences in pre-event water contribution between headwaters and different events; and (2) to relate these differences to rainfall, catchment, and antecedent characteristics.
METHODS
Study area
The study area, the Zwäckentobel, is a pre-alpine catchment in Switzerland and approximately 40 km south of Zurich. The climate is humid with a mean annual temperature of 6 °C. The mean annual precipitation is 2,300 mm y−1, of which half falls during the snow-free season (June–October). It rains approximately every second day and about one-third of the annual precipitation falls as snow (Stähli & Gustafsson 2006). The mean annual actual evaporation is approximately 300 mm y−1 (Menzel et al. 2007). The mountain streams respond quickly and can have high discharges with large amounts of sediment transport (Turowski et al. 2009). After rainfall events, the streams return to baseflow within approximately 1 day.
Catchment characteristics of the Zwäckentobel and its five headwaters
. | . | . | . | ZT . | WS04 . | WS7 . | WS10 . | WS11 . | WS19 . |
---|---|---|---|---|---|---|---|---|---|
Shape | Size | km2 | 4.25 | 0.7 | 0.21 | 0.23 | 0.09 | 0.15 | |
Altitude | Max | m | 1,656 | 1,656 | 1,656 | 1,598 | 1,583 | 1,598 | |
Mean | 1,360 | 1,342 | 1,468 | 1,432 | 1,421 | 1,494 | |||
Min | 1,084 | 1,109 | 1,262 | 1,276 | 1,292 | 1,384 | |||
Slope | Mean | ° | 19 | 17 | 21 | 23 | 24 | 18 | |
Max | 56 | 49 | 47 | 53 | 45 | 43 | |||
Geology | Flysch | Waegitaler | % | 29 | 64 | 16 | 0 | 0 | 0 |
Wild | 17 | 29 | 42 | 0 | 0 | 0 | |||
Schlieren | 54 | 7 | 42 | 100 | 100 | 100 | |||
Soil depth | <1 m | % | 29 | 44 | 55 | 73 | 74 | 49 | |
Land cover | Forest | % | 55 | 53 | 53 | 72 | 81 | 18 | |
Partly forested | 21 | 22 | 27 | 14 | 10 | 1 | |||
Meadow | 24 | 25 | 20 | 14 | 9 | 81 | |||
Wetland | % | 29 | 33 | 28 | 23 | 21 | 51 |
. | . | . | . | ZT . | WS04 . | WS7 . | WS10 . | WS11 . | WS19 . |
---|---|---|---|---|---|---|---|---|---|
Shape | Size | km2 | 4.25 | 0.7 | 0.21 | 0.23 | 0.09 | 0.15 | |
Altitude | Max | m | 1,656 | 1,656 | 1,656 | 1,598 | 1,583 | 1,598 | |
Mean | 1,360 | 1,342 | 1,468 | 1,432 | 1,421 | 1,494 | |||
Min | 1,084 | 1,109 | 1,262 | 1,276 | 1,292 | 1,384 | |||
Slope | Mean | ° | 19 | 17 | 21 | 23 | 24 | 18 | |
Max | 56 | 49 | 47 | 53 | 45 | 43 | |||
Geology | Flysch | Waegitaler | % | 29 | 64 | 16 | 0 | 0 | 0 |
Wild | 17 | 29 | 42 | 0 | 0 | 0 | |||
Schlieren | 54 | 7 | 42 | 100 | 100 | 100 | |||
Soil depth | <1 m | % | 29 | 44 | 55 | 73 | 74 | 49 | |
Land cover | Forest | % | 55 | 53 | 53 | 72 | 81 | 18 | |
Partly forested | 21 | 22 | 27 | 14 | 10 | 1 | |||
Meadow | 24 | 25 | 20 | 14 | 9 | 81 | |||
Wetland | % | 29 | 33 | 28 | 23 | 21 | 51 |
Map of the Zwäckentobel: (a) sampling locations in selected headwaters WS04 to WS19; (b) geology: three different types of flysch and on top the shallow soils ≤1 m indicated as hatched areas; (c) land cover: forest and meadows with hatched areas indicating wetlands. Colour scheme of (b) and (c) adapted from www.ColorBrewer.org. Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
Map of the Zwäckentobel: (a) sampling locations in selected headwaters WS04 to WS19; (b) geology: three different types of flysch and on top the shallow soils ≤1 m indicated as hatched areas; (c) land cover: forest and meadows with hatched areas indicating wetlands. Colour scheme of (b) and (c) adapted from www.ColorBrewer.org. Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
The geology of the Zwäckentobel has three different types of tertiary flysch: Wild, Waeggitaler, and Schlieren flysch. The different facies consist of different calcareous sedimentary layers of schist, marl or sandstone (Hantke 1967; Hsü & Briegel 1991) with creeping gleysols (0.5–2.5 m) on top (Figure 1(b)). The spatial distribution of shallow soils (depth ≤1 m) was taken from Fischer et al. (2015). The soils have a high silt and clay content resulting in a low matrix permeability but a high drainage capacity in macropores and the organic layer of 20–50 cm (Feyen et al. 1999).
The land cover of the Zwäckentobel was classified by Fischer et al. (2015) into forest, partly forested, meadows, and wetlands (Figure 1(c)). The dominant tree species in the Zwäckentobel is Norway spruce with a plate-shaped root network with an approximate root depth of 1 meter, in wet areas. Non-forested locations within the catchment are generally wetter and consist of bushed and/or swampy meadows or wetlands (Rinderer et al. 2012). During the summer months, meadows in the upper part (above 1,450 m) of WS04 and WS19 are used as alpine pastures.
Instrumentation
Precipitation was measured at 14 locations (Figure 1(a)). Two of the rain gauges are situated in the Erlenbach catchment (WS04) and have been measuring precipitation since 1964 (WG-01: Ott Pluvio, OTT Hydrometrie AG, Switzerland and TB-14: Joss-Tognini tipping bucket, Lamprecht meteo, Germany). The remaining 12 rain gauges (Davis II rain collector-tipping bucket; Davis Instruments Corp., USA with Odyssey data logger; Dataflow Systems, New Zealand) were distributed over the Zwäckentobel in the open field at a height of 1.5 m above ground level and measured rainfall during the period 2009–2011. Barometric pressure and air temperature were measured at WG-01 and WS19 (Keller DCX-22, Keller AG, Switzerland; Figure 1(a)).
In the Erlenbach catchment (WS04), stage/discharge has been measured with a concrete flume from 1984 to the present (Hegg et al. 2006). The headwaters WS07, WS10, WS11, and WS19 and the Zwäckentobel outlet (ZT) were gauged in 2009 (Keller DCX-22 pressure and temperature sensors, Keller AG, Switzerland, Figure 1(a)). Due to the frequently changing stream morphologies it was impossible to derive rating curves. In the vicinity of WG-01, groundwater levels have been measured since 1992 in a screened groundwater well and with an Ott-groundwater data logger (OTT Hydrometrie AG, Switzerland; Figure 1(a)).
Event sampling
Hydrometeorological characteristics of the 13 sampled events
Event nr. . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | |||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . |
ADS [d] | 7 | 1 | 5 | 2 | 3 | 5 | 1 | 2 | 3 | 0 | 0 | 1 | 14 |
API7 [mm] | 2 | 50 | 6 | 10 | 24 | 5 | 41 | 23 | 2 | 10 | 9 | 26 | 0 |
AGL1 [cm] | −34 | −23 | −28 | −19 | −28 | −36 | −12 | −28 | −38 | −41 | −37 | −23 | −42 |
AQ1 [l s−1 km−2] | 7 | 16 | 3 | 7 | 10 | 7 | 11 | 7 | 1 | 4 | 0 | 13 | 1 |
P length [h] | 10 | 8 | 70 | 10 | 23 | 11 | 30 | 37 | 2 | 19 | 11 | 11 | 33 |
Psum [mm] | 22 (2.6) | 11 (1.4) | 109 (16) | 10 (1) | 84 (19) | 25 (1.5) | 56 (17) | 50 (15) | 11.8 (2) | 20.4 (1) | 51 (11) | 25 (2) | 31(12) |
P[mm h−1] | 2.2(0.3) | 1.3 (0.2) | 1.5 (0.2) | 0.9 (0.1) | 3.6 (0.9) | 2.5 (0.2) | 2 (0.6) | 1.4 (0.4) | 6 (1) | 1 (0.1) | 1.9 (0.4) | 1.6 (0.2) | 0.9 (0.4) |
Pmax [mm h−1] | 4.5 (0.6) | 2.3 (0.3) | 7.6 (1.1) | 2.4 (0.4) | 18 (8.4) | 9 (0.9) | 6.7 (1.6) | 10 (2.7) | 10 (3) | 7.3 (0.7) | 7 (1.4) | 6 (1.4) | 8.6 (3.5) |
Hresponds [h] | 0.6 (1) | 1 (0.6) | 0.2 (0) | 0.3 (0.3) | 0.2 (0.1) | 0.1 (0.1) | 0.3 (0.2) | 0.7 (0.3) | 0.1 (0.1) | 0.4 (0.3) | 0.3 (0.2) | 0.3 (0.2) | 1.3 (0.5) |
Qpeak [l s−1 km−2] | 353 | 106 | 1,010 | 53 | 3,004 | 390 | 1,197 | 1,287 | 86 | 334 | 589 | 504 | 509 |
Q/P [-] | 0.35 | 0.36 | 0.7 | 0.29 | 0.6 | 0.25 | 0.68 | 0.55 | 0.12 | 0.25 | 0.52 | 0.52 | 0.28 |
Event nr. . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | |||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . |
ADS [d] | 7 | 1 | 5 | 2 | 3 | 5 | 1 | 2 | 3 | 0 | 0 | 1 | 14 |
API7 [mm] | 2 | 50 | 6 | 10 | 24 | 5 | 41 | 23 | 2 | 10 | 9 | 26 | 0 |
AGL1 [cm] | −34 | −23 | −28 | −19 | −28 | −36 | −12 | −28 | −38 | −41 | −37 | −23 | −42 |
AQ1 [l s−1 km−2] | 7 | 16 | 3 | 7 | 10 | 7 | 11 | 7 | 1 | 4 | 0 | 13 | 1 |
P length [h] | 10 | 8 | 70 | 10 | 23 | 11 | 30 | 37 | 2 | 19 | 11 | 11 | 33 |
Psum [mm] | 22 (2.6) | 11 (1.4) | 109 (16) | 10 (1) | 84 (19) | 25 (1.5) | 56 (17) | 50 (15) | 11.8 (2) | 20.4 (1) | 51 (11) | 25 (2) | 31(12) |
P[mm h−1] | 2.2(0.3) | 1.3 (0.2) | 1.5 (0.2) | 0.9 (0.1) | 3.6 (0.9) | 2.5 (0.2) | 2 (0.6) | 1.4 (0.4) | 6 (1) | 1 (0.1) | 1.9 (0.4) | 1.6 (0.2) | 0.9 (0.4) |
Pmax [mm h−1] | 4.5 (0.6) | 2.3 (0.3) | 7.6 (1.1) | 2.4 (0.4) | 18 (8.4) | 9 (0.9) | 6.7 (1.6) | 10 (2.7) | 10 (3) | 7.3 (0.7) | 7 (1.4) | 6 (1.4) | 8.6 (3.5) |
Hresponds [h] | 0.6 (1) | 1 (0.6) | 0.2 (0) | 0.3 (0.3) | 0.2 (0.1) | 0.1 (0.1) | 0.3 (0.2) | 0.7 (0.3) | 0.1 (0.1) | 0.4 (0.3) | 0.3 (0.2) | 0.3 (0.2) | 1.3 (0.5) |
Qpeak [l s−1 km−2] | 353 | 106 | 1,010 | 53 | 3,004 | 390 | 1,197 | 1,287 | 86 | 334 | 589 | 504 | 509 |
Q/P [-] | 0.35 | 0.36 | 0.7 | 0.29 | 0.6 | 0.25 | 0.68 | 0.55 | 0.12 | 0.25 | 0.52 | 0.52 | 0.28 |
Antecedent dry spell (ADS), antecedent precipitation index with 7 days prior to an event (API7), antecedent groundwater level (AGL1), antecedent discharge (AQ1), rainfall duration (P length), mean event rainfall sum all rain gauges (Psum), mean average hourly rainfall intensity of all rain gauges (P), maximum hourly rainfall intensity of all rain gauges (Pmax), mean stream responds to rainfall of all headwaters (H responds), maximum specific discharge of WS04 (Qpeak), runoff coefficient (Q/P). Spatial standard deviation is in brackets.
For WS04–WS19 and events 1–13 the number of stream samples n Cs, δ18O [‰] of pre-event water Cpe, maximum and minimum event water Ce and maximum and minimum streamwater, IHS based minimum fraction of pre-event water fPE and its corresponding uncertainty . The letters np indicate events where an IHS was not possible
Event . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | ||||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . | |
WS04 | Cpe | −10.5 | −10.4 | −10.7 | −8.45 | −9.12 | −8.5 | −8.5 | −8.51 | −8.96 | −9.01 | −9.41 | ||
Ce − WG01 | −4.6 | −8.39 | −4.61 | −6.89 | −6.89 | −4.26 | −2.9 | −5.39 | −3.15 | −4.37 | −8.89 | |||
−6.63 | −16.4 | −9.35 | −8.95 | −8.95 | −15.22 | −5.27 | −7.59 | −13.33 | −11.77 | −10.47 | ||||
n Cs | 23 | 46 | 23 | 15 | 26 | 45 | 10 | 20 | 26 | 29 | 21 | |||
Cs | −9.59 | −10.4 | −7.03 | −8.67 | −8.67 | −8.76 | −8.51 | −8.08 | −8.3 | −8.01 | −9.39 | |||
−10.53 | −12.94 | −8.81 | −9.73 | −9.73 | −10.32 | −8.82 | −9.23 | −9.28 | −9.07 | −9.8 | ||||
fPE | 0.83 | 0.1 | 0.28 | np | 0.48 | 0.32 | 0.91 | 0.57 | 0.84 | 0.51 | np | |||
![]() | ±0.1 | ±0.87 | ±0.16 | ±0.3 | ±0.8 | ±0.35 | ±0.3 | ±0.16 | ±0.24 | |||||
WS07 | Cpe | −10.64 | −10.6 | −9.39 | −9.39 | −9.49 | −9.39 | |||||||
n Cs | 24 | 49 | 34 | 9 | 24 | 20 | ||||||||
Cs | −8.84 | −8.84 | −8.84 | −9.08 | −8.31 | −9.33 | ||||||||
−10.48 | −10.48 | −10.48 | −10.13 | −9.49 | −9.85 | |||||||||
fPE | np | 0.1 | 0.61 | np | np | 0.29 | ||||||||
![]() | ±0.87 | ±0.14 | ||||||||||||
WS10 | Cpe | −10.64 | −10.42 | −10.7 | −9.43 | −9.35 | −9.36 | −10.24 | −8.45 | −8.95 | −9.756 | −9.73 | ||
Ce − TB06 | −8.32 | −8.87 | −7.35 | −4.61 | −3.43 | −3.75 | −2.36 | −4.96 | −3.75 | −4.64 | −5.36 | |||
−11.63 | −20.4 | −8.7 | −9.35 | −9.05 | −14.19 | −5.68 | −7.52 | −12.67 | −11.88 | −10.43 | ||||
n Cs | 24 | 53 | 24 | 35 | 7 | 6 | 8 | 10 | 20 | 23 | 24 | |||
Cs | −10.35 | −10.42 | −10.27 | −7.38 | −7.86 | −8.95 | −8.4 | −8.27 | −8.17 | −8.65 | −9.19 | |||
−10.79 | −12.42 | −10.88 | −9.44 | −9.82 | −10.03 | −10.24 | −8.75 | −9.52 | −9.76 | −10.19 | ||||
fPE | np | 0.36 | 0.84 | 0.55 | 0.42 | np | 0.67 | 0.84 | np | 0.6 | np | |||
![]() | ±0.34 | ±0.24 | ±0.16 | ±0.35 | ±0.15 | ±0.6 | ±0.19 | |||||||
WS11 | Cpe | −10.52 | −9.964 | −9.11 | −10.5 | −9 | −9.89 | −9.7 | ||||||
n Cs | 54 | 15 | 15 | 20 | 23 | 18 | 24 | |||||||
Cs | −10.16 | −8.99 | −8.95 | −7.92 | −8.35 | −8.65 | −9.16 | |||||||
−12.29 | −9.33 | −9.85 | −10.5 | −9.33 | −9.18 | −10.18 | ||||||||
fPE | 0.49 | np | np | 0.6 | 0.86 | 0.57 | 0.74 | |||||||
![]() | ±0.25 | ±0.1 | ±0.17 | ±0.17 | ±0.29 | |||||||||
WS19 | Cpe | −10.46 | −10.19 | −10.26 | −11.3 | −9.1 | −8.9 | −8.79 | −8.4 | |||||
Ce − TB10 | −8.13 | −5.74 | −8.88 | −7.72 | −5.3 | −5.7 | −4.75 | −6.32 | ||||||
−11.8 | −7.87 | −17.33 | −9.06 | −9.56 | −9.66 | −10.88 | −12.14 | |||||||
n Cs | 24 | 23 | 54 | 24 | 34 | 13 | 22 | 23 | ||||||
Cs | −9.8 | −8.92 | −10.26 | −10.35 | −6.82 | −8.55 | −7.08 | −8.71 | ||||||
−11.04 | −10.46 | −14.32 | −10.89 | −8.54 | −8.75 | −8.8 | −9.73 | |||||||
fPE | 0.6 | 0.68 | 0.1 | 0.7 | 0.3 | np | 0.51 | 0.33 | ||||||
![]() | ±0.1 | ±0.13 | ±0.73 | ±0.1 | ±0.14 | ±0.4 | ±0.2 |
Event . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | ||||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . | |
WS04 | Cpe | −10.5 | −10.4 | −10.7 | −8.45 | −9.12 | −8.5 | −8.5 | −8.51 | −8.96 | −9.01 | −9.41 | ||
Ce − WG01 | −4.6 | −8.39 | −4.61 | −6.89 | −6.89 | −4.26 | −2.9 | −5.39 | −3.15 | −4.37 | −8.89 | |||
−6.63 | −16.4 | −9.35 | −8.95 | −8.95 | −15.22 | −5.27 | −7.59 | −13.33 | −11.77 | −10.47 | ||||
n Cs | 23 | 46 | 23 | 15 | 26 | 45 | 10 | 20 | 26 | 29 | 21 | |||
Cs | −9.59 | −10.4 | −7.03 | −8.67 | −8.67 | −8.76 | −8.51 | −8.08 | −8.3 | −8.01 | −9.39 | |||
−10.53 | −12.94 | −8.81 | −9.73 | −9.73 | −10.32 | −8.82 | −9.23 | −9.28 | −9.07 | −9.8 | ||||
fPE | 0.83 | 0.1 | 0.28 | np | 0.48 | 0.32 | 0.91 | 0.57 | 0.84 | 0.51 | np | |||
![]() | ±0.1 | ±0.87 | ±0.16 | ±0.3 | ±0.8 | ±0.35 | ±0.3 | ±0.16 | ±0.24 | |||||
WS07 | Cpe | −10.64 | −10.6 | −9.39 | −9.39 | −9.49 | −9.39 | |||||||
n Cs | 24 | 49 | 34 | 9 | 24 | 20 | ||||||||
Cs | −8.84 | −8.84 | −8.84 | −9.08 | −8.31 | −9.33 | ||||||||
−10.48 | −10.48 | −10.48 | −10.13 | −9.49 | −9.85 | |||||||||
fPE | np | 0.1 | 0.61 | np | np | 0.29 | ||||||||
![]() | ±0.87 | ±0.14 | ||||||||||||
WS10 | Cpe | −10.64 | −10.42 | −10.7 | −9.43 | −9.35 | −9.36 | −10.24 | −8.45 | −8.95 | −9.756 | −9.73 | ||
Ce − TB06 | −8.32 | −8.87 | −7.35 | −4.61 | −3.43 | −3.75 | −2.36 | −4.96 | −3.75 | −4.64 | −5.36 | |||
−11.63 | −20.4 | −8.7 | −9.35 | −9.05 | −14.19 | −5.68 | −7.52 | −12.67 | −11.88 | −10.43 | ||||
n Cs | 24 | 53 | 24 | 35 | 7 | 6 | 8 | 10 | 20 | 23 | 24 | |||
Cs | −10.35 | −10.42 | −10.27 | −7.38 | −7.86 | −8.95 | −8.4 | −8.27 | −8.17 | −8.65 | −9.19 | |||
−10.79 | −12.42 | −10.88 | −9.44 | −9.82 | −10.03 | −10.24 | −8.75 | −9.52 | −9.76 | −10.19 | ||||
fPE | np | 0.36 | 0.84 | 0.55 | 0.42 | np | 0.67 | 0.84 | np | 0.6 | np | |||
![]() | ±0.34 | ±0.24 | ±0.16 | ±0.35 | ±0.15 | ±0.6 | ±0.19 | |||||||
WS11 | Cpe | −10.52 | −9.964 | −9.11 | −10.5 | −9 | −9.89 | −9.7 | ||||||
n Cs | 54 | 15 | 15 | 20 | 23 | 18 | 24 | |||||||
Cs | −10.16 | −8.99 | −8.95 | −7.92 | −8.35 | −8.65 | −9.16 | |||||||
−12.29 | −9.33 | −9.85 | −10.5 | −9.33 | −9.18 | −10.18 | ||||||||
fPE | 0.49 | np | np | 0.6 | 0.86 | 0.57 | 0.74 | |||||||
![]() | ±0.25 | ±0.1 | ±0.17 | ±0.17 | ±0.29 | |||||||||
WS19 | Cpe | −10.46 | −10.19 | −10.26 | −11.3 | −9.1 | −8.9 | −8.79 | −8.4 | |||||
Ce − TB10 | −8.13 | −5.74 | −8.88 | −7.72 | −5.3 | −5.7 | −4.75 | −6.32 | ||||||
−11.8 | −7.87 | −17.33 | −9.06 | −9.56 | −9.66 | −10.88 | −12.14 | |||||||
n Cs | 24 | 23 | 54 | 24 | 34 | 13 | 22 | 23 | ||||||
Cs | −9.8 | −8.92 | −10.26 | −10.35 | −6.82 | −8.55 | −7.08 | −8.71 | ||||||
−11.04 | −10.46 | −14.32 | −10.89 | −8.54 | −8.75 | −8.8 | −9.73 | |||||||
fPE | 0.6 | 0.68 | 0.1 | 0.7 | 0.3 | np | 0.51 | 0.33 | ||||||
![]() | ±0.1 | ±0.13 | ±0.73 | ±0.1 | ±0.14 | ±0.4 | ±0.2 |
For WS04–WS19 and events 1–13 the number of stream samples n Cs, δ2H [‰] of pre-event water Cpe, maximum and minimum event water Ce and maximum and minimum streamwater, IHS based minimum fraction of pre-event water fPE and its corresponding uncertainty . The letters np indicate events where an IHS was not possible
Event . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | ||||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . | |
WS04 | Cpe | −66.8 | −72.4 | −68.7 | −66.5 | −62.1 | −64.6 | −57.1 | −60.6 | −59.8 | −56.9 | −61 | ||
Ce − WG01 | −26.1 | −53.6 | −25.4 | −46.1 | −21.8 | −25.6 | −19.7 | −29.7 | −17.3 | −20.8 | −60.3 | |||
−45.1 | −123.0 | −64.1 | −59.8 | −52.6 | −115.6 | −24.9 | −47.6 | −96.0 | −103.6 | −73.2 | ||||
n Cs | 23 | 46 | 23 | 15 | 26 | 45 | 10 | 20 | 26 | 29 | 21 | |||
Cs | −64.5 | −71.2 | −47.3 | −57.6 | −46.8 | −59.7 | −57.4 | −53.8 | −55.6 | −52.9 | −62.6 | |||
−72.3 | −92.4 | −61.4 | −66.5 | −62.1 | −73.6 | −59.5 | −62.4 | −62.98 | −61.0 | −66.4 | ||||
fPE | 0.85 | 0.1 | 0.34 | np | 0.51 | 0.26 | 0.65 | 0.65 | 0.9 | 0.52 | np | |||
![]() | ±0.12 | ±0.88 | ±0.17 | ±0.26 | ±0.9 | ±0.35 | ±0.34 | ±0.2 | ±0.24 | |||||
WS07 | Cpe | −71 | −73.2 | −58.7 | −64.6 | −60.9 | −60.9 | |||||||
n Cs | 24 | 49 | 34 | 9 | 24 | 20 | ||||||||
Cs | −69.8 | −72.5 | −51.4 | −62.4 | −54.9 | −62.4 | ||||||||
−74.2 | −90.6 | −62.6 | −69.6 | −64.4 | −67.4 | |||||||||
fPE | np | 0.1 | 0.72 | np | np | 0.29 | ||||||||
![]() | ±0.8 | ±0.18 | ||||||||||||
WS10 | Cpe | −73.8 | −72.3 | −71.3 | −72.1 | −68.5 | −64.6 | −70.9 | −57.5 | −63.3 | −60.9 | −66.7 | ||
Ce − TB06 | −54.1 | −29 | −55.1 | −49.5 | −29.3 | −20.3 | −18.3 | −28.1 | −23.2 | −23.8 | −32.8 | |||
−77.8 | −34.4 | −153.7 | −62.9 | −60.9 | −107.7 | −27.9 | −45.7 | −89.6 | −82.6 | −68.8 | ||||
n Cs | 24 | 53 | 24 | 35 | 7 | 6 | 8 | 10 | 20 | 23 | 24 | |||
Cs | −69.9 | |||||||||||||
−71.3 | −71.1 | −47.5 | −51.6 | −62.4 | −54.5 | −55.2 | −56.1 | −64.2 | −60.6 | |||||
−75.1 | −89.1 | −74.7 | −63.8 | −68.5 | −69.3 | −70.9 | −58.9 | −64.2 | −57.1 | −63.8 | ||||
fPE | np | 0.32 | 0.9 | 0.55 | 0.39 | np | 0.66 | 0.84 | np | 0.59 | np | |||
![]() | ±0.58 | ±0.37 | ±0.16 | ±0.36 | ±0.1 | ±0.39 | ±0.19 | |||||||
WS11 | Cpe | −72.2 | −62.2 | −64.6 | −72.1 | −58.3 | −57.6 | −60.3 | ||||||
n Cs | 54 | 15 | 15 | 20 | 23 | 18 | 24 | |||||||
Cs | −70.8 | −60.9 | −65 | −48.3 | −55.7 | −57.1 | −60.8 | |||||||
−88.5 | −64.1 | −68.7 | −72.1 | −63.4 | −67.7 | −69.8 | ||||||||
fPE | 0.36 | np | np | 0.55 | 0.8 | 0.57 | 0.74 | |||||||
![]() | ±0.53 | ±0.1 | ±0.28 | ±0.17 | ±0.29 | |||||||||
WS19 | Cpe | −69.8 | −69.4 | −70.2 | −74.9 | −47.2 | −66.5 | −46.6 | −57.5 | |||||
Ce − TB10 | −50.7 | −33.6 | −55.3 | −50.3 | −31 | −15 | −23.9 | −39.2 | ||||||
−77.1 | −49.4 | −127.9 | −63.9 | −67.6 | −61.8 | −70.2 | −82.5 | |||||||
n Cs | 24 | 23 | 54 | 24 | 34 | 13 | 22 | 23 | ||||||
Cs | −67.7 | −60.7 | −69.9 | −71.8 | −42.6 | −55.9 | −46.7 | −57.8 | ||||||
−72.8 | −71.7 | −104.3 | −75.4 | −57.3 | −58.7 | −60.1 | −65.9 | |||||||
fPE | 0.68 | 0.75 | 0.1 | 0.87 | 0.6 | np | 0.47 | 0.33 | ||||||
![]() | ±0.1 | ±0.14 | ±0.8 | ±0.27 | ±0.35 | ±0.15 | ±0.2 |
Event . | 1 . | 2 . | 3 . | 4 . | 5 . | 6 . | 7 . | 8 . | 9 . | 10 . | 11 . | 12 . | 13 . | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Year . | 2010 . | 2011 . | ||||||||||||
Day, month . | 8 Sep . | 17 Sep . | 24 Sep . | 4 Oct . | 29 Jun . | 8 Jul . | 14 Jul . | 15 Aug . | 24 Aug . | 27 Aug . | 4 Sep . | 18 Sep . | 6 Oct . | |
WS04 | Cpe | −66.8 | −72.4 | −68.7 | −66.5 | −62.1 | −64.6 | −57.1 | −60.6 | −59.8 | −56.9 | −61 | ||
Ce − WG01 | −26.1 | −53.6 | −25.4 | −46.1 | −21.8 | −25.6 | −19.7 | −29.7 | −17.3 | −20.8 | −60.3 | |||
−45.1 | −123.0 | −64.1 | −59.8 | −52.6 | −115.6 | −24.9 | −47.6 | −96.0 | −103.6 | −73.2 | ||||
n Cs | 23 | 46 | 23 | 15 | 26 | 45 | 10 | 20 | 26 | 29 | 21 | |||
Cs | −64.5 | −71.2 | −47.3 | −57.6 | −46.8 | −59.7 | −57.4 | −53.8 | −55.6 | −52.9 | −62.6 | |||
−72.3 | −92.4 | −61.4 | −66.5 | −62.1 | −73.6 | −59.5 | −62.4 | −62.98 | −61.0 | −66.4 | ||||
fPE | 0.85 | 0.1 | 0.34 | np | 0.51 | 0.26 | 0.65 | 0.65 | 0.9 | 0.52 | np | |||
![]() | ±0.12 | ±0.88 | ±0.17 | ±0.26 | ±0.9 | ±0.35 | ±0.34 | ±0.2 | ±0.24 | |||||
WS07 | Cpe | −71 | −73.2 | −58.7 | −64.6 | −60.9 | −60.9 | |||||||
n Cs | 24 | 49 | 34 | 9 | 24 | 20 | ||||||||
Cs | −69.8 | −72.5 | −51.4 | −62.4 | −54.9 | −62.4 | ||||||||
−74.2 | −90.6 | −62.6 | −69.6 | −64.4 | −67.4 | |||||||||
fPE | np | 0.1 | 0.72 | np | np | 0.29 | ||||||||
![]() | ±0.8 | ±0.18 | ||||||||||||
WS10 | Cpe | −73.8 | −72.3 | −71.3 | −72.1 | −68.5 | −64.6 | −70.9 | −57.5 | −63.3 | −60.9 | −66.7 | ||
Ce − TB06 | −54.1 | −29 | −55.1 | −49.5 | −29.3 | −20.3 | −18.3 | −28.1 | −23.2 | −23.8 | −32.8 | |||
−77.8 | −34.4 | −153.7 | −62.9 | −60.9 | −107.7 | −27.9 | −45.7 | −89.6 | −82.6 | −68.8 | ||||
n Cs | 24 | 53 | 24 | 35 | 7 | 6 | 8 | 10 | 20 | 23 | 24 | |||
Cs | −69.9 | |||||||||||||
−71.3 | −71.1 | −47.5 | −51.6 | −62.4 | −54.5 | −55.2 | −56.1 | −64.2 | −60.6 | |||||
−75.1 | −89.1 | −74.7 | −63.8 | −68.5 | −69.3 | −70.9 | −58.9 | −64.2 | −57.1 | −63.8 | ||||
fPE | np | 0.32 | 0.9 | 0.55 | 0.39 | np | 0.66 | 0.84 | np | 0.59 | np | |||
![]() | ±0.58 | ±0.37 | ±0.16 | ±0.36 | ±0.1 | ±0.39 | ±0.19 | |||||||
WS11 | Cpe | −72.2 | −62.2 | −64.6 | −72.1 | −58.3 | −57.6 | −60.3 | ||||||
n Cs | 54 | 15 | 15 | 20 | 23 | 18 | 24 | |||||||
Cs | −70.8 | −60.9 | −65 | −48.3 | −55.7 | −57.1 | −60.8 | |||||||
−88.5 | −64.1 | −68.7 | −72.1 | −63.4 | −67.7 | −69.8 | ||||||||
fPE | 0.36 | np | np | 0.55 | 0.8 | 0.57 | 0.74 | |||||||
![]() | ±0.53 | ±0.1 | ±0.28 | ±0.17 | ±0.29 | |||||||||
WS19 | Cpe | −69.8 | −69.4 | −70.2 | −74.9 | −47.2 | −66.5 | −46.6 | −57.5 | |||||
Ce − TB10 | −50.7 | −33.6 | −55.3 | −50.3 | −31 | −15 | −23.9 | −39.2 | ||||||
−77.1 | −49.4 | −127.9 | −63.9 | −67.6 | −61.8 | −70.2 | −82.5 | |||||||
n Cs | 24 | 23 | 54 | 24 | 34 | 13 | 22 | 23 | ||||||
Cs | −67.7 | −60.7 | −69.9 | −71.8 | −42.6 | −55.9 | −46.7 | −57.8 | ||||||
−72.8 | −71.7 | −104.3 | −75.4 | −57.3 | −58.7 | −60.1 | −65.9 | |||||||
fPE | 0.68 | 0.75 | 0.1 | 0.87 | 0.6 | np | 0.47 | 0.33 | ||||||
![]() | ±0.1 | ±0.14 | ±0.8 | ±0.27 | ±0.35 | ±0.15 | ±0.2 |
For WS04, sampled events 2 and 11. The top panels show the δ18O in event water (dark line), streamwater (grey squares), pre-event water (triangle), and air temperature (dashed line). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles and grey area below the hydrograph).
For WS04, sampled events 2 and 11. The top panels show the δ18O in event water (dark line), streamwater (grey squares), pre-event water (triangle), and air temperature (dashed line). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles and grey area below the hydrograph).
Water sample analysis
The collected water samples were analyzed for their stable isotope composition at the stable isotope laboratory of the University of Zurich, Department of Geography. All water samples were filtered (0.45 μm filter 25 mm PTFE Syringe Filter, Simplepure USA) and pipetted in a vial (1 mL into a 1.5 mL 32 × 11.6 mm screw neck vials with cap and PTFE/silicone/PTFE septa) prior to analysis. Samples were analyzed with a Cavity Ring-Down Spectroscope-Picarro L1102-i Liquid Analyser (1st generation analyser, Picarro Inc. 2008). The analysis scheme of Penna et al. (2010) was followed, and values were reported as δ-values in per mille (‰) relative to Vienna Standard Mean Ocean Water. Most samples could be measured with a precision for δ2H of <0.5‰ and for δ18O of <0.1‰. Due to some technical issues with the spectroscope, for some samples the accuracy for δ2H was >1‰ while for δ18O it remained <0.1‰.
IHS
Data analysis
Peakflow exceedance curve (WS04, Qpeak >33 l s−1 km−2), event rainfall sum distribution (WG-01, Psum >5 mm) for the period 1998–201,1 and where circles indicate the sampled events 1–13.
Peakflow exceedance curve (WS04, Qpeak >33 l s−1 km−2), event rainfall sum distribution (WG-01, Psum >5 mm) for the period 1998–201,1 and where circles indicate the sampled events 1–13.
In addition to standard representation of the IHS (hydrograph, precipitation, air temperature, stable isotope, and calculated pre-event water), we related the rainfall characteristics, antecedent conditions, and baseflow, 1 day before an event (WS04), to the observed minimum (near the maximum discharge) using a linear relation to explain differences in pre-event water. Additionally, five types of multiple linear regression were performed, where for each type, the rainfall characteristics, antecedent conditions, and baseflow 1 day before an event (WS04), were added stepwise to relate to the observed minimum
to explain differences in pre-event water.
RESULTS
Sampled event characterization
Antecedent discharge (closed circles) and antecedent groundwater level (open circles) against antecedent precipitation index for the sampled events 1–13.
Antecedent discharge (closed circles) and antecedent groundwater level (open circles) against antecedent precipitation index for the sampled events 1–13.
Stable isotopes and hydrograph separation of sampled storm events
(a) Inset: all collected rainfall samples (grey circles) and stream samples (black circles) of all headwaters and events follow the global meteoric water line. (b) Values of the minimum fraction of pre-event water computed based on δ18O observations versus the corresponding values that were computed based on δ2H observations for the different events and catchments (each catchment is represented by a different colour). The grey line is where pre-event water computations based on δ18O and δ2H observations would be equal. Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
(a) Inset: all collected rainfall samples (grey circles) and stream samples (black circles) of all headwaters and events follow the global meteoric water line. (b) Values of the minimum fraction of pre-event water computed based on δ18O observations versus the corresponding values that were computed based on δ2H observations for the different events and catchments (each catchment is represented by a different colour). The grey line is where pre-event water computations based on δ18O and δ2H observations would be equal. Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
Hydrometric and δ18O overview of WS04-W19 and events 1–13. The top panels show δ18O in event water (open circles and colours indicate different rain gauges), streamwater (grey squares) and pre-event water (triangle). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles). Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
Hydrometric and δ18O overview of WS04-W19 and events 1–13. The top panels show δ18O in event water (open circles and colours indicate different rain gauges), streamwater (grey squares) and pre-event water (triangle). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles). Please refer to the online version of this paper to see this figure in colour: http://dx.doi.org/10.2166/nh.2016.176.
The minimum fraction of pre-event water (fPE) for the different streams and events varied from 0.01 up to 0.9 and occurred half an hour before or after a maximum water level (Figure 6). For some events, the rainfall, pre-event, or streamwater sample compositions were too similar to allow the fraction of pre-event water to be calculated (Table 3). In events where IHS was possible, the uncertainties in the minimum fraction of pre-event water (WfPE) were between ±0.1 up to ±0.9 (Table 3).
Comparison of three headwaters and events
Spatial distribution of event rainfall [mm] for (a) event 3, (b) event 5, and (c) event 12. Circles indicate rain gauges where text indicates the maximum event rainfall intensity [mm h−1]. The headwater areal event rainfall [mm] is listed in brackets. Crosses indicate technical failures of rain gauges or sequential samplers. (d), (e), and (f) indicate the accumulated event rainfall [mm] of the different rain gauges in WS04, WS10, and WS19.
Spatial distribution of event rainfall [mm] for (a) event 3, (b) event 5, and (c) event 12. Circles indicate rain gauges where text indicates the maximum event rainfall intensity [mm h−1]. The headwater areal event rainfall [mm] is listed in brackets. Crosses indicate technical failures of rain gauges or sequential samplers. (d), (e), and (f) indicate the accumulated event rainfall [mm] of the different rain gauges in WS04, WS10, and WS19.
Detailed hydrometric and δ18O overview of headwaters WS04, WS10, and W19 and event 3, 5, and 12. The top panels show δ18O in event water (line), streamwater (grey squares), pre-event water (triangle), and air temperature (dashed line). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles and grey area below the hydrograph).
Detailed hydrometric and δ18O overview of headwaters WS04, WS10, and W19 and event 3, 5, and 12. The top panels show δ18O in event water (line), streamwater (grey squares), pre-event water (triangle), and air temperature (dashed line). Bottom panels show precipitation (inverted, from the top), water level (solid dark line), and fraction of pre-event water fpe (circles and grey area below the hydrograph).
In event 5, the rainfall amount and intensities increased from WS04 towards WS19 (Table 2 and Figure 7(b) and 7(e)) and the hydrograph had two peaks (Figure 8, middle column). The δ18O in event water of sampler WG-1 and TB-6 had a similar range, but were temporally different, while TB-10 was more depleted (Table 3 and Figure 8, middle column). The δ18O in pre-event water and streamwater samples in WS04 and WS10 were alike and became more enriched towards the first peak of the hydrograph, while WS19 was more depleted. In all streams, the fraction of pre-event water decreased rapidly towards the first peak and increased during the intra-event of 6 hours. With the onset of the rain, the streams responded fast and WS04 had the highest recorded discharge of the 13 events sampled (Figure 2). The fraction of pre-event water was 0.3 for WS04 and WS19, during the first and second peak. In WS10, the fraction of pre-event water during the first peak was 0.72 and decreased during the second peak to 0.55. After the maximum water level the different automatic water samplers were full, and were not restarted, and therefore further observations were missing.
Event 12 had an average and evenly distributed event rainfall sum and intensity (Table 2 and Figure 7(c) and 7(f)) and the hydrograph had multiple peaks (Figure 8, right column). The δ18O in event water of sampler WG-1 and TB-10 were alike, while more depleted in TB-06 (Table 3 and Figure 8, right column). The δ18O in pre-event water in WS04, WS10, and WS19 were alike and the streamwater increased on average 1‰ during events. The rising limb was not sampled due to technical problems and started just at the maximum water level. The three different headwaters had fractions of pre-event water ranging from 0.51 to 0.6 and increased gradually during the falling limb to 1 (Table 3 and Figure 8, right column).
Explanatory factors of pre-event water fractions
Multiple linear relation of pre-event water and different predictors
. | R2 . | F . | p . |
---|---|---|---|
WS04, WS07, WS10, WS11, WS19 | |||
fPE min = 0.80–0.01 Psum | 0.50 | 30 | <0.001 |
fPE min = 0.71–0.02 Pmax | 0.13 | 4.25 | 0.04 |
fPE min = 0.43–0.06 API7 | 0.03 | 1.1 | 0.3 |
fPE min = 0.42–0.004 AGL1 | 0.02 | 0.7 | 0.4 |
fPE min = 0.52–0.003 AQ1 | 0.002 | 6.2 | 0.02 |
fPE min = 0.91–0.01 Psum–0.02 Pmax | 0.53 | 16.2 | <0.001 |
fPE min = 0.91–0.01 Psum–0.02 Pmax–0.004 API7 | 0.53 | 10.4 | <0.001 |
fPE min = 0.91–0.01 Psum–0.02 Pmax–0.004 API7 + 0.001AGL1 | 0.58 | 9.3 | <0.001 |
fPE min = 0.87–0.01 Psum–0.02 Pmax–0.001 API7 + 0.004AGL1–0.002AQ1 | 0.64 | 8.9 | <0.001 |
WS04 fPE min = 0.92–0.01 Psum | 0.87 | 49.9 | <0.001 |
fPE min = 0.99–0.01 Psum–0.01 Pmax | 0.88 | 24.7 | <0.001 |
WS07 fPE min = 1.1–0.01 Psum | np | ||
fPE min = 1.1–0.01 Psum +0.01 Pmax | np | ||
WS10 fPE min = 0.83–0.01 Psum | 0.80 | 20.2 | <0.001 |
fPE min = 0.88–0.001 Psum–0.01 Pmax | 0.82 | 9.07 | <0.1 |
WS11 fPE min = 0.8–0.003 Psum | 0.02 | 0.04 | 0.85 |
fPE min = 0.85–0.003 Psum–0.001 Pmax | 0.02 | 0.01 | 0.98 |
WS19 fPE min = 0.73–0.01 Psum | 0.94 | 65 | <0.001 |
fPE min = 0.78–0.001 Psum–0.02 Pmax | 0.99 | >100 | <0.001 |
. | R2 . | F . | p . |
---|---|---|---|
WS04, WS07, WS10, WS11, WS19 | |||
fPE min = 0.80–0.01 Psum | 0.50 | 30 | <0.001 |
fPE min = 0.71–0.02 Pmax | 0.13 | 4.25 | 0.04 |
fPE min = 0.43–0.06 API7 | 0.03 | 1.1 | 0.3 |
fPE min = 0.42–0.004 AGL1 | 0.02 | 0.7 | 0.4 |
fPE min = 0.52–0.003 AQ1 | 0.002 | 6.2 | 0.02 |
fPE min = 0.91–0.01 Psum–0.02 Pmax | 0.53 | 16.2 | <0.001 |
fPE min = 0.91–0.01 Psum–0.02 Pmax–0.004 API7 | 0.53 | 10.4 | <0.001 |
fPE min = 0.91–0.01 Psum–0.02 Pmax–0.004 API7 + 0.001AGL1 | 0.58 | 9.3 | <0.001 |
fPE min = 0.87–0.01 Psum–0.02 Pmax–0.001 API7 + 0.004AGL1–0.002AQ1 | 0.64 | 8.9 | <0.001 |
WS04 fPE min = 0.92–0.01 Psum | 0.87 | 49.9 | <0.001 |
fPE min = 0.99–0.01 Psum–0.01 Pmax | 0.88 | 24.7 | <0.001 |
WS07 fPE min = 1.1–0.01 Psum | np | ||
fPE min = 1.1–0.01 Psum +0.01 Pmax | np | ||
WS10 fPE min = 0.83–0.01 Psum | 0.80 | 20.2 | <0.001 |
fPE min = 0.88–0.001 Psum–0.01 Pmax | 0.82 | 9.07 | <0.1 |
WS11 fPE min = 0.8–0.003 Psum | 0.02 | 0.04 | 0.85 |
fPE min = 0.85–0.003 Psum–0.001 Pmax | 0.02 | 0.01 | 0.98 |
WS19 fPE min = 0.73–0.01 Psum | 0.94 | 65 | <0.001 |
fPE min = 0.78–0.001 Psum–0.02 Pmax | 0.99 | >100 | <0.001 |
Minimum fraction of pre-event water (fPE min), event rainfall sum (Psum), maximum hourly rainfall intensity (Pmax), antecedent precipitation index with 7 days prior to an event (API7), antecedent groundwater level (AGL1), antecedent discharge (AQ1) of WS04.
The event rainfall sum related to the minimum fraction of pre-event water fpe (left) and max rainfall intensity related to the minimum fraction of pre-event water fpe (right) for WS04, WS10, and WS19. Different sizes of circles indicate different antecedent conditions (wet, average, and dry) and numbers refer to events 3, 5, and 12.
The event rainfall sum related to the minimum fraction of pre-event water fpe (left) and max rainfall intensity related to the minimum fraction of pre-event water fpe (right) for WS04, WS10, and WS19. Different sizes of circles indicate different antecedent conditions (wet, average, and dry) and numbers refer to events 3, 5, and 12.
The runoff coefficient for catchment WS04 as a function of the event rainfall sum (WG-01). The line illustrates the Burch et al. (1996) derived relation between runoff coefficient and event rainfall sum. Each circle indicates one of the 12 events of this study. The circle size of closed circles indicates the minimum fraction of pre-event water of WS04. Open circles refer to events where IHS was not possible or isotope data were not sampled.
The runoff coefficient for catchment WS04 as a function of the event rainfall sum (WG-01). The line illustrates the Burch et al. (1996) derived relation between runoff coefficient and event rainfall sum. Each circle indicates one of the 12 events of this study. The circle size of closed circles indicates the minimum fraction of pre-event water of WS04. Open circles refer to events where IHS was not possible or isotope data were not sampled.
DISCUSSION
Assessment of pre-event water contribution
In our studied headwaters, we observed large spatial variability in rainfall sum, intensity, and stable isotope composition for the large events, over relatively short distances (100 m). The spatiotemporal variability of δ18O in event water was larger compared to the spatial variability of δ18O in pre-event water and streamwater samples. These observations support the idea that small forested headwaters are often erroneously assumed to have homogeneous rainfall patterns (Goodrich et al. 1995) and isotopic compositions of precipitation (Lyon et al. 2008; Holko et al. 2012). Lyon et al. (2009) found that the spatial and temporal variability of the isotope composition may result in different fractions of pre-event water, depending on the use of δ18O or δ2H in the IHS. In this study, however, the differences between fractions of pre-event water computed based on δ18O and δ2H were smaller (±10%) compared to the large difference reported by Lyon et al. (2009). Furthermore, the differences in fraction of pre-event water using δ18O or δ2H were generally smaller than the IHS error propagation estimates. The large uncertainties were the result of, as Genereux (1998) suggested, small differences in δ18O between event water and pre-event water. Large differences in δ18O between event and pre-event isotopic composition are generally expected in summer months and therefore summer is considered as the favorable season to perform an IHS (Vitvar & Balderer 1997). This benefit however, was not always so strong for the 13 studied events and an IHS was not always possible. This could have been caused by the altitude of the studied headwaters above 1,100 m. This altitude resulted in a temperature decrease towards 0 °C with snowfall, even during summer, for certain events. The lower temperatures resulted in a more depleted isotopic composition compared to the average seasonal isotopic compositions. With high soil surface temperatures, the snow melted immediately and contributed to runoff generation. Late summer events, such as event 3 or 13, had lower air temperatures and the snow cover persisted, acting as an extra storage of precipitation. As a consequence, the stormflow magnitude in relation to its rainfall sum decreased. During snowmelt no fractionation was observed in stream samples. However, we cannot exclude that fractionated melt water was diluted by pre-event water, or that snow melt contributed to delayed stream flow.
The isotope composition of rainfall was sampled with a higher resolution compared to many other studies (e.g., sampling locations, temporal resolution, and events). Nonetheless, due to the observed spatial variability of stable isotopes in precipitation and stream samples, using the nearest rain gauge for each headwater in the IHS might have introduced an incomplete accounting of event water in space and time, as described by Buttle (1994). This might have been the case for large events with large spatial gradients of rainfall amounts, intensities, and stable isotopes. Furthermore, forest interception and throughfall can result in changed isotopic signatures (Saxena 1987; Allen et al. 2015). Since the rainfall was sampled only in the open field this might have influenced the IHS results. Despite the incomplete sampling of rainfall and uncertainties in the fraction of pre-event water, the general pattern of fast response and recession of the hydrograph, and fraction of pre-event water, were analogous with plot scale tracer experiments by Feyen et al. (1999) and Weiler et al. (1998, 1999) and two events described by Weiler et al. (1999). Our study observed a high variability in fraction of pre-event water between the different events, which is opposite to the perception that humid-forested headwaters have dominant pre-event water during the peak discharge (Buttle 1994). This underlines the idea that when neglecting the spatial and temporal variability of rainfall characteristics and isotopic composition, one might get an incomplete picture of runoff processes.
Rainfall as a dominant factor in runoff processes
The frequent rainfall marked the headwater's wet character and its spatiotemporal dynamic. The fast hydraulic response of the streams and decrease of the fraction of pre-event water indicated the strong connection between rainfall and runoff. A statistical evaluation of controlling mechanisms was not possible because of the irregularly sampled data set (due to technical and logistic constraints). Instead, the minimum fraction of pre-event water was available for most sampled events. Buttle (1994) used the minimum fraction of pre-event water to compare different studies around the world and concluded that pre-event water dominated the peak discharges. Similarly, the minimum fraction of pre-event water was used in our study watersheds to compare processes that occur during the peak discharge. Despite the uncertainty, the minimum fraction of pre-event water, used as a qualitative proxy, indicated the overall pre-event or event water contribution during stormflow and could be related to explanatory variables. Rodhe (1987) found a decreasing relation of fraction of pre-event water with increasing snowmelt (for six headwaters distributed throughout Sweden with 2–6 snowmelt events per headwater). A similar decreasing relation of the fraction of pre-event water with increasing rainfall sums was observed for plot scale experiments (Weiler et al. 1999; Kienzler & Naef 2008), in a single urban catchment (Pellerin et al. 2008), and in a single pre-alpine headwater (Penna et al. 2014). Our study confirmed this relation and proved the validity in neighboring headwaters with different catchment characteristics (WS04–WS19). Renshaw et al. (2003) instead described a positive relation of the fraction of pre-event water with increasing precipitation, which might be caused by the smaller event rainfall sums and resulted in dominant pre-event water contribution. Considering all sampled events of WS04–WS19, the minimum fraction of pre-event water largely depended on the rainfall sum and, to a smaller degree, on the rainfall intensity. For individual streams the relation of minimum fraction of pre-event water and rainfall sum was even stronger. In WS07 and WS11, the fewer possible IHS did not allow for a statistical analysis. However, it is likely that in these headwaters the rainfall sum would also be a strongest predictor. The strong relation of rainfall sum and the fraction of pre-event water together with the spatial distribution of rainfall explained to a large degree the differences in pre-event water of WS04-WS19.
Compared to Blume et al. (2007), the error made by separating the hydrograph of WS04 into fast flow and baseflow was small due to the clear difference in antecedent baseflow and higher (by orders of magnitudes) stormflow. The runoff coefficient of the different sampled events in WS04 was also similar to the power law defined by Burch et al. (1996). Separating the runoff into fast flow and baseflow is extensively criticized (Klaus & McDonnell 2013), since it does not represent the observed dominant pre-event water contribution in forest headwaters (Buttle 1994; McGlynn et al. 2002). However, the combination of the runoff coefficient with the minimum pre-event water contribution, provides additional useful information. Instead of separating the hydrograph into fast and slow runoff processes, the runoff coefficient described the volume of discharge produced due to a certain amount of precipitation. In combination with the IHS, it became visible that the volume of discharge contained a certain fraction of event water and both similarly increased with increasing precipitation.
Catchment characteristics as secondary factors in runoff processes
The observed variable fraction of pre-event water in WS04-WS19 was different compared to the more stable observations made in catchments with a similarly high annual precipitation amount (>2,000 mm y−1) such as the Maimai (McGlynn et al. 2002) or H. J. Andrews catchment (McGuire & McDonnell 2010). The differences in fraction of pre-event water might be due to the differences in land cover. The Maimai and H. J. Andrews catchment are predominantly forested compared to the mixed land cover (meadows, forests, and large percentage of wetlands 20–50%) of the Zwäckentobel. A higher pre-event water contribution was observed in stormflow of forested catchments compared to wetlands (McCartney et al. 1998; Laudon et al. 2007) or grasslands (Bonell et al. 1990). Plot scale experiments found differences in runoff processes for different soils (Feyen et al. 1999) and land covers (Weiler et al. 1998). However, no strong relation between the fraction of pre-event water and land cover could be noticed when comparing WS04–WS19 with each other. A small influence of land cover on runoff processes was noticeable for only some events. In WS10 and WS11 (steeper slopes, shallow soils, smaller amount of wetland, and large forested areas), for the larger events, a slightly higher pre-event water contribution and additional weaker relation of pre-event water with rainfall was observed compared with WS04, WS07, and WS19. Instead, a faster response with higher event water contribution was noted in WS19 (constantly grazed short grass, compacted topsoil layer with low infiltration, storage and interception compared with natural grass).
Another factor that might explain the differences in pre-event water between the Maimai and H. J. Andrews catchment and the Zwäckentobel, are the different subsurface characteristics. The vertical cracks of the Maimai and more permeable soil types of the H. J. Andrews facilitate rain water infiltration and fill up the subsurface topography resulting in a subsurface threshold with dominant pre-event water. The Zwäckentobel instead has shallow gleysols with a low matrix permeability, small active storage, and dominant stormflow in the organic soil horizon (20–50 cm), similar to the soils of a nearby hillslope described by Schneider et al. (2014). In the Zwäckentobel, a typical riparian zone was lacking but the large areas of wetlands were prominent elements of passive storage (Fischer et al. 2015). These elements are activated during the rainfall events and release the stored pre-event water. With increasing rainfall sum, at approximately 50 mm, a change from pre-event dominated to event dominated runoff was found (Figure 10). Hydrometric and isotopic observations of the soil profile were missing. However, we hypothesize that with increasing rainfall the shallow soils saturate and reach, at approximately 50 mm, the maximum storage capacity of the soil (in agreement with soil water retention and moisture information before and during plot scale sprinkling experiments by Feyen et al. (1996, 1999)). As a result, the distributed wetlands fully connect through preferential flowpaths (creeping soils, animal burrows, or old roots and ephemeral streams), any additional rainfall by-passes the shallow soils and participates in streamflow. This would explain that with increasing precipitation, the amount of runoff produced by the precipitation increases and the fraction of pre-event water decreased. The variable rainfall with additional small storage (organic soil horizon, 20–50 cm) results in a near surface-dependent threshold with subsequently more variable pre-event water contribution, showing similarities to the Babinda model described by Bonell et al. (1998). The connectivity of distributed wetlands is better described by the hydrogeomorphic model of Sidle et al. (2000), where spatially distributed passive sources progressively become active and connected with the flow network.
Beside the previously described implicit role of catchment characteristics in runoff processes, no relationship between the fraction of pre-event water and catchment characteristics was found in WS04–WS19 or the study of Burch et al. (1996) or Taylor & Pearce (1982). A reason could be that in events where observations (stream response and runoff processes) and explanatory variables (precipitation and catchment characteristics) are both spatially variable, it is difficult to determine the dominant influencing factor on runoff processes. Furthermore, it was likely that the frequent precipitation together with the catchment characteristics meant that the headwater was in a continuous wet state; therefore, any potential influence of catchment characteristics on runoff processes was not visible in the data. A similar reduced effect of wet antecedent conditions and flow through the upper soil horizon was observed by Shanley et al. (2002). This may also explain why, despite each event having different antecedent wetness conditions, no clear relation of pre-event water contribution and antecedent proxies was observed. This is opposite to the findings of Shanley et al. (2002), Casper et al. (2003), Pellerin et al. (2008) and James & Roulet (2009). Furthermore, we did not observe a seasonal change in fraction of pre-event water as had been observed in different pre-alpine headwaters (McGuire & McDonnell 2010; Penna et al. 2014).
The IHS gave good qualitative information on the contribution of rainfall and the fraction of pre-event water, nevertheless many questions on the flowpath, the runoff (Lyon et al. 2008), and thresholds (Graham et al. 2010) are unresolved. Future studies should validate the connectivity, interaction, and different runoff processes of the headwater internal catchment elements (such as wetlands or forest). A multiple tracer approach (using similar tracers used by Fischer et al. (2015), δ18O, Ca and DOC) would allow better understanding of the flowpaths and contributing sources during stormflow of headwaters, while a finer temporal sampling resolution would help investigate subtle changes in pre-event water in relation to differences in catchment characteristics.
CONCLUSION
In this study, 13 rainfall–runoff events of different magnitude and intensity were analyzed in five neighboring steep and rainfall dominated headwaters, to assess the pre-event water contribution. The combination of long-term and spatially short-term hydrometeorological measurements, together with event water sampling in different neighboring streams and multiple events, complemented each other and helped to overcome individual limitations.
The pre-event water contribution was found to be temporally variable and depended on rainfall amount and intensity. Small events had high pre-event water contribution. With increasing precipitation, the volume of runoff produced by precipitation increased and a change from pre-event to event water dominated runoff processes occurred. The variable rainfall amount and small active storage (organic soil horizon, 20–50 cm) resulted in a threshold in the upper soil horizon with subsequently more variable pre-event water contribution.
Despite the differences in catchment characteristics between the neighboring streams at headwater scale, no significant difference in minimum fraction of pre-event water contribution was observed. Furthermore, none of the antecedent wetness proxies had any explanatory value on the minimum fraction of pre-event water. This can be explained by the frequent precipitation and by the catchment characteristics keeping the soil in a wet state.
In contrast to the conventional approach (i.e., studying one headwater with few events), our results highlight the necessity to study different neighboring headwaters and a wide range of event magnitudes (many events and many samples), to better understand the dynamic character and controlling factors in runoff processes.
ACKNOWLEDGEMENTS
We thank all the people who helped in the field and the laboratory. Especially we thank Ilaria Clemenzi, Michael Rinderer, Martin Šanda, Russel Smith, Stefan Plötner, Stephan Müller, Karl Steiner, Andrea Kolleger, Ellen Cerwinka, Sandra Pool, Sandra Schärer, Nadja Lavanga, Seraina Kauer, Jana Dusik, Paribesh Pradhan, Andrea Ruecker, Yves Götz, Annagreth Schuler and Werni Ruhstaller, Bruno Kägi, Claudia Schreiner, Michael Hilf, Sandra Röthlisberger, and Ivan Woodhatch. We thank Tracy Ewen for proofreading the manuscript, the editor and two anonymous reviewers provided helpful comments, which helped to clarify the text. We also thank the Oberallmeindkorporation Schwyz (OAK), the Department of Environment of the Canton of Schwyz and the municipality Alpthal for their helpful cooperation.