A simple co-precipitation technique is proposed for synthesis of tin oxide (SnO2) microrods. Stannous chloride and urea were used during synthesis. X-ray powder diffraction (XRD) analysis revealed that the annealed product consists of SnO2 microrods having tetragonal unit cells, while scanning electron microscopy (SEM) analysis revealed the rod-like morphology of a synthesized product. These synthesized microrods are used as photocatalyst for the degradation of reactive black 5 (RB5). Degradation kinetics of RB5 are monitored under daylight in different concentrations of hydrogen peroxide (H2O2) and catalyst. The percentage of RB5 conversion is also calculated at various concentrations of hydrogen peroxide and catalyst which demonstrate that RB5 shows high catalytic degradation at high concentrations of hydrogen peroxide and catalyst.