Data from the laboratory-scale column studies (shown in
Figures 7 and
8) show pH-sorted soluble Mn
2+ concentrations as a function of temperature for the 10-cm media depth and the 25-cm media depth, respectively. As was seen in the full-scale Harwood's Mill data evaluation, a decrease in water temperature yielded a decreased ability of the MnO
x(s)-coated media to remove soluble Mn
2+ at either media depth. In general, as both the temperature and pH decreased, the soluble Mn
2+ concentration in the column increased. For example, soluble Mn
2+ concentrations at 5 °C were higher for data in the pH range of 6.0–6.5 than data in the pH range of 6.5–7.0. It should be noted that soluble Mn
2+ concentrations were below the recommended target of 0.015 mg/L at temperatures below 10 °C for pH conditions greater than 7.5. Data presented in Table 1 show mean soluble Mn
2+ concentration as a function of pH under low water temperature conditions (4–7 °C) for the laboratory-scale data. As shown in Table 1, soluble Mn
2+ concentration decreased with an increase in solution pH.
Table 1Mean soluble Mn concentration as a function of pH for temperatures between 4 and 7 °C
. | Soluble Mn concentration (μg/L)
. |
---|
pH range
. | 10-cm media depth
. | 25-cm media depth
. |
---|
<6.0 | 141 | 126 |
6.0–6.5 | 67 | 63 |
6.5–7.0 | 53 | 39 |
7.0–7.5 | 38 | 25 |
>7.5 | 8 | 6 |
. | Soluble Mn concentration (μg/L)
. |
---|
pH range
. | 10-cm media depth
. | 25-cm media depth
. |
---|
<6.0 | 141 | 126 |
6.0–6.5 | 67 | 63 |
6.5–7.0 | 53 | 39 |
7.0–7.5 | 38 | 25 |
>7.5 | 8 | 6 |
Figure 7
pH sorted laboratory-scale filter effluent soluble Mn concentration as a function of solution temperature for a 10-cm media depth.
Figure 7
pH sorted laboratory-scale filter effluent soluble Mn concentration as a function of solution temperature for a 10-cm media depth.
Figure 8
pH sorted laboratory-scale filter effluent soluble Mn concentration as a function of temperature for a 25-cm media depth.
Figure 8
pH sorted laboratory-scale filter effluent soluble Mn concentration as a function of temperature for a 25-cm media depth.