Table 1

Lake Geneva (G3). Results of All data concentration and IEL (integrated element load) trends before and after 2006 (Gd only after 2006). Values in bold are significant (p < 0.05). In IELs, slopes in italics are significant only when Hamed and Rao correction is not applied

 All dataZaSlopea/ng L1 y1bIELZaHamed Rao ZaSlope/μg y1cYearly increasee/% yr1
 NN
Cd         
Before 2006 1,080 0.96 108 −0.16 −0.16 −0.017 (− 0.35–0.27) −0.47 
After 2006 1,150 18.4 0.38 (0.34–0.42) 113 6.70 4.58 0.29 (0.21–0.36) 15 
Co         
Before 2006 1,053 0.11 105 0.094 0.086 0.088 (− 1.4–1.6) 0.14 
After 2006 1,150 7.10 3.1 (2.2–3.9) 114 2.24 1.21 2.2 (0.254.1) 2.6 
Gd         
After 2006 1,093 19.5 0.15 (0.13–0.17) 109 7.26 4.58 0.14 (0.11–0.16) 20 
Mo         
Before 2006 1,080 12.2 30 (25–34) 108 4.24 1.80 21 (11–31) 1.9 
After 2006 1,142 22.1 17 (16–18) 113 7.52 4.24 11 (9.2–13) 1.2 
Pb         
Before 2001 600 −3.67 −1.7 (− 1.7–0) 60 2.23 1.62 4.7 (− 9.9–0.41) 22 
After 2001 1,608 −2.64 −0.0068 (− 0.030–0) 157 0.39 −0.48 −0.11 (− 0.48–0.18) −1.8 
Sb         
Before 2006 1,079 5.83 1.8 (1.2–2.3) 107 1.96 1.21 0.94 (0–1.8) 1.0 
After 2006 1,150 29.6 3.1 (2.9–3.2) 114 10.1 4.60 2.2 (2.0–2.5) 3.7 
Sr         
Before 2006 1,080 1.40 7.5 (7.1–7.7) 108 1.55 d 5.3 (5.255.4) 1.5 
After 2006 1,143 1.38 0.95 (0.93–1.0) 114 1.22 d 0.65 (0.610.67) 0.21 
 All dataZaSlopea/ng L1 y1bIELZaHamed Rao ZaSlope/μg y1cYearly increasee/% yr1
 NN
Cd         
Before 2006 1,080 0.96 108 −0.16 −0.16 −0.017 (− 0.35–0.27) −0.47 
After 2006 1,150 18.4 0.38 (0.34–0.42) 113 6.70 4.58 0.29 (0.21–0.36) 15 
Co         
Before 2006 1,053 0.11 105 0.094 0.086 0.088 (− 1.4–1.6) 0.14 
After 2006 1,150 7.10 3.1 (2.2–3.9) 114 2.24 1.21 2.2 (0.254.1) 2.6 
Gd         
After 2006 1,093 19.5 0.15 (0.13–0.17) 109 7.26 4.58 0.14 (0.11–0.16) 20 
Mo         
Before 2006 1,080 12.2 30 (25–34) 108 4.24 1.80 21 (11–31) 1.9 
After 2006 1,142 22.1 17 (16–18) 113 7.52 4.24 11 (9.2–13) 1.2 
Pb         
Before 2001 600 −3.67 −1.7 (− 1.7–0) 60 2.23 1.62 4.7 (− 9.9–0.41) 22 
After 2001 1,608 −2.64 −0.0068 (− 0.030–0) 157 0.39 −0.48 −0.11 (− 0.48–0.18) −1.8 
Sb         
Before 2006 1,079 5.83 1.8 (1.2–2.3) 107 1.96 1.21 0.94 (0–1.8) 1.0 
After 2006 1,150 29.6 3.1 (2.9–3.2) 114 10.1 4.60 2.2 (2.0–2.5) 3.7 
Sr         
Before 2006 1,080 1.40 7.5 (7.1–7.7) 108 1.55 d 5.3 (5.255.4) 1.5 
After 2006 1,143 1.38 0.95 (0.93–1.0) 114 1.22 d 0.65 (0.610.67) 0.21 

aAll calculated by MK, except Sr (SMK). 95% confidence intervals are for all Sen's slopes' values in MK calculations and for Sen's slopes' seasonal median values in SMK calculations; thus they are not directly comparable.

bExcept for Sr, in μg L−1 y−1.

cExcept for Sr, in mg y−1.

dHamed and Rao correction not needed because SMK includes serial correlation correction.

eYearly increase = 100 × Sen's slope/median IEL (2006).

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