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Table 3

Degradation rate and half-lives of imidacloprid (1 mg/L) at different concentrations of ZnO and H2O2 concentration of 20 mM at pH 7

ProcessConcentration of ZnODegradation rate constant, k, (min−1)Half-life t1/2 (min)
ZnO(normal)/H2O2/artificial sunlight 100 mg/L 0.0046 ± 0.0001 149.18 ± 1.25e 
500 mg/L 0.0073 ± 0.00002 94.48 ± 1.34c 
1,000 mg/L 0.0080 ± 0.00003 85.89 ± 2.65b 
ZnO(nano)/H2O2/artificial sunlight 100 mg /L 0.0071 ± 0.00004 97.41 ± 3.17cd 
500 mg/L 0.0076 ± 0.0001 91.43 ± 1.87c 
1,000 mg/L 0.0095 ± 0.0001 72.68 ± 2.35a 
ProcessConcentration of ZnODegradation rate constant, k, (min−1)Half-life t1/2 (min)
ZnO(normal)/H2O2/artificial sunlight 100 mg/L 0.0046 ± 0.0001 149.18 ± 1.25e 
500 mg/L 0.0073 ± 0.00002 94.48 ± 1.34c 
1,000 mg/L 0.0080 ± 0.00003 85.89 ± 2.65b 
ZnO(nano)/H2O2/artificial sunlight 100 mg /L 0.0071 ± 0.00004 97.41 ± 3.17cd 
500 mg/L 0.0076 ± 0.0001 91.43 ± 1.87c 
1,000 mg/L 0.0095 ± 0.0001 72.68 ± 2.35a 

Statistical comparisons were made among treatments within a single column.

The different letters represent significant differences using Fisher's LSD test at P0.05.

Data presented in mean value (three replicates) ± standard deviation.

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