Degradation rate and half-lives of imidacloprid (1 mg/L) at different concentrations of ZnO and H2O2 concentration of 20 mM at pH 7
Process . | Concentration of ZnO . | Degradation rate constant, k, (min−1) . | Half-life t1/2 (min) . |
---|---|---|---|
ZnO(normal)/H2O2/artificial sunlight | 100 mg/L | 0.0046 ± 0.0001 | 149.18 ± 1.25e |
500 mg/L | 0.0073 ± 0.00002 | 94.48 ± 1.34c | |
1,000 mg/L | 0.0080 ± 0.00003 | 85.89 ± 2.65b | |
ZnO(nano)/H2O2/artificial sunlight | 100 mg /L | 0.0071 ± 0.00004 | 97.41 ± 3.17cd |
500 mg/L | 0.0076 ± 0.0001 | 91.43 ± 1.87c | |
1,000 mg/L | 0.0095 ± 0.0001 | 72.68 ± 2.35a |
Process . | Concentration of ZnO . | Degradation rate constant, k, (min−1) . | Half-life t1/2 (min) . |
---|---|---|---|
ZnO(normal)/H2O2/artificial sunlight | 100 mg/L | 0.0046 ± 0.0001 | 149.18 ± 1.25e |
500 mg/L | 0.0073 ± 0.00002 | 94.48 ± 1.34c | |
1,000 mg/L | 0.0080 ± 0.00003 | 85.89 ± 2.65b | |
ZnO(nano)/H2O2/artificial sunlight | 100 mg /L | 0.0071 ± 0.00004 | 97.41 ± 3.17cd |
500 mg/L | 0.0076 ± 0.0001 | 91.43 ± 1.87c | |
1,000 mg/L | 0.0095 ± 0.0001 | 72.68 ± 2.35a |
Statistical comparisons were made among treatments within a single column.
The different letters represent significant differences using Fisher's LSD test at P≤0.05.
Data presented in mean value (three replicates) ± standard deviation.