A high correlation was observed between Ni–Cu (0.71), Pb–Ni (0.94), Cr–Ni (0.88), Cd–Cu (0.75), Ni–Cu (0.71), Pb–Cr (0.88) (Table 4 and Figure 3). Accordingly, metals were classified into three main groups: first group – Cu, Pb, Ni, Cd, Cr; second group – Al, Zn, Fe; and third group – Mn. Considering the above classification it is evident that metals were grouped according to their origin, i.e. metals with natural origin (second group) and metals originating by anthropogenic activities (first and third groups) (Lippmann 1999).
Correlation matrix of elements
. | Al . | Zn . | Fe . | Cu . | Cr . | Mn . | Ni . | Pb . |
---|---|---|---|---|---|---|---|---|
Zn | 0.53 | |||||||
Fe | 0.16 | 0.36 | ||||||
Cu | 0.23 | 0.01 | 0.27 | |||||
Cr | 0.17 | −0.21 | −0.17 | 0.58 | ||||
Mn | 0.00 | −0.01 | −0.25 | −0.22 | −0.19 | |||
Ni | 0.18 | −0.22 | −0.16 | 0.71 | 0.88 | −0.20 | ||
Pb | 0.16 | −0.11 | −0.15 | 0.65 | 0.82 | −0.19 | 0.94 | |
Cd | 0.17 | −0.23 | −0.10 | 0.75 | 0.55 | −0.27 | 0.63 | 0.44 |
. | Al . | Zn . | Fe . | Cu . | Cr . | Mn . | Ni . | Pb . |
---|---|---|---|---|---|---|---|---|
Zn | 0.53 | |||||||
Fe | 0.16 | 0.36 | ||||||
Cu | 0.23 | 0.01 | 0.27 | |||||
Cr | 0.17 | −0.21 | −0.17 | 0.58 | ||||
Mn | 0.00 | −0.01 | −0.25 | −0.22 | −0.19 | |||
Ni | 0.18 | −0.22 | −0.16 | 0.71 | 0.88 | −0.20 | ||
Pb | 0.16 | −0.11 | −0.15 | 0.65 | 0.82 | −0.19 | 0.94 | |
Cd | 0.17 | −0.23 | −0.10 | 0.75 | 0.55 | −0.27 | 0.63 | 0.44 |
Values in bold present positive correlation that exist between metals, mainly related to their origin in water.
Calculation of ADDi × 10−6 (mg/kg/day)
Sample . | Al . | Zn . | Fe . | Cu . | Cr . | Mn . | Ni . | Pb . | Cd . |
---|---|---|---|---|---|---|---|---|---|
Tap water – Student's city | 690 | 510 | 600 | 370 | 25 | 2.6 | 140 | 26 | 2.3 |
Tragjasi reservoir | 1,400 | 720 | 370 | 220 | 49 | 22 | 390 | 66 | 1.7 |
Llogaraja spring | 1,100 | 320 | 110 | 140 | 34 | 0 | 320 | 52 | 1.5 |
Tragjas spring | 1,100 | 400 | 0 | 220 | 45 | 9.9 | 400 | 51 | 2.0 |
Tap water – Tirana city | 6,100 | 700 | 500 | 280 | 49 | 16 | 290 | 48 | 1.7 |
Trebeshina (0.5 L) | 2,700 | 57 | 87 | 380 | 72 | 2.9 | 1,100 | 91 | 3.8 |
Trebeshina (1.5 L) | 650 | 19 | 0 | 460 | 84 | 11 | 1,100 | 100 | 3.8 |
Living (sparkle 0.5 L) | 930 | 45 | 32 | 140 | 55 | 2.6 | 250 | 36 | 2.0 |
BI (0.5 L) | 2,400 | 41 | 130 | 440 | 72 | 11 | 1,200 | 84 | 3.5 |
Lajthiza (0.5 L) | 1,500 | 58 | 140 | 26 | 17 | 26 | 45 | 2.6 | 1.7 |
Qafeshtama (0.5 L) | 340 | 33 | 160 | 46 | 74 | 0 | 1,100 | 14 | 1.7 |
Glina (sparkle 0.5 L) | 1,600 | 21 | 100 | 590 | 130 | 3.2 | 26,000 | 350 | 2.9 |
Dukat (0.5 L) | 470 | 52 | 0 | 68 | 39 | 0 | 270 | 39 | 2.0 |
Dukat (1.5 L) | 240 | 24 | 0 | 120 | 21 | 2.0 | 230 | 51 | 1.5 |
Tepelena (0.5 L) | 400 | 46 | 490 | 110 | 35 | 0 | 220 | 25 | 1.7 |
Tepelena (1.5 L) | 240 | 16 | 0 | 140 | 34 | 0 | 190 | 19 | 1.7 |
Spring (0.5 L) | 720 | 29 | 12 | 150 | 44 | 0 | 190 | 39 | 1.5 |
Evian | 510 | 1.2 | 620 | 360 | 62 | 8.4 | 600 | 51 | 1.7 |
Frassassi | 220 | 2.0 | 460 | 260 | 51 | 5.5 | 650 | 51 | 2.3 |
Aqua Pana | 810 | 87 | 490 | 0 | 28 | 2.0 | 170 | 45 | 2.9 |
Sample . | Al . | Zn . | Fe . | Cu . | Cr . | Mn . | Ni . | Pb . | Cd . |
---|---|---|---|---|---|---|---|---|---|
Tap water – Student's city | 690 | 510 | 600 | 370 | 25 | 2.6 | 140 | 26 | 2.3 |
Tragjasi reservoir | 1,400 | 720 | 370 | 220 | 49 | 22 | 390 | 66 | 1.7 |
Llogaraja spring | 1,100 | 320 | 110 | 140 | 34 | 0 | 320 | 52 | 1.5 |
Tragjas spring | 1,100 | 400 | 0 | 220 | 45 | 9.9 | 400 | 51 | 2.0 |
Tap water – Tirana city | 6,100 | 700 | 500 | 280 | 49 | 16 | 290 | 48 | 1.7 |
Trebeshina (0.5 L) | 2,700 | 57 | 87 | 380 | 72 | 2.9 | 1,100 | 91 | 3.8 |
Trebeshina (1.5 L) | 650 | 19 | 0 | 460 | 84 | 11 | 1,100 | 100 | 3.8 |
Living (sparkle 0.5 L) | 930 | 45 | 32 | 140 | 55 | 2.6 | 250 | 36 | 2.0 |
BI (0.5 L) | 2,400 | 41 | 130 | 440 | 72 | 11 | 1,200 | 84 | 3.5 |
Lajthiza (0.5 L) | 1,500 | 58 | 140 | 26 | 17 | 26 | 45 | 2.6 | 1.7 |
Qafeshtama (0.5 L) | 340 | 33 | 160 | 46 | 74 | 0 | 1,100 | 14 | 1.7 |
Glina (sparkle 0.5 L) | 1,600 | 21 | 100 | 590 | 130 | 3.2 | 26,000 | 350 | 2.9 |
Dukat (0.5 L) | 470 | 52 | 0 | 68 | 39 | 0 | 270 | 39 | 2.0 |
Dukat (1.5 L) | 240 | 24 | 0 | 120 | 21 | 2.0 | 230 | 51 | 1.5 |
Tepelena (0.5 L) | 400 | 46 | 490 | 110 | 35 | 0 | 220 | 25 | 1.7 |
Tepelena (1.5 L) | 240 | 16 | 0 | 140 | 34 | 0 | 190 | 19 | 1.7 |
Spring (0.5 L) | 720 | 29 | 12 | 150 | 44 | 0 | 190 | 39 | 1.5 |
Evian | 510 | 1.2 | 620 | 360 | 62 | 8.4 | 600 | 51 | 1.7 |
Frassassi | 220 | 2.0 | 460 | 260 | 51 | 5.5 | 650 | 51 | 2.3 |
Aqua Pana | 810 | 87 | 490 | 0 | 28 | 2.0 | 170 | 45 | 2.9 |