It is found strong positive correlations between turbidity with color (r = 0.756) and nitrite with chloride (r = 0.887) and TDS (r = 0.761). Nitrate and nitrite predominantly resulting due to man-made activities (Marghade et al. 2021). As nitrite is positively linked with chloride both ions have the same source, i.e. anthropogenic activities. It is revealed that fluoride has a moderate negative correlation (r = –0.729) with the pH value of the water as tabulated in Table 3. Fluoride absorption in soils reduced from humid to dry regions and from acidic to alkaline soils (Wang et al. 2002; Balasooriya et al. 2021). Furthermore, fluoride, pH, and total alkalinity occupied a separate parameter loading in PCA (Table 5). Thus, this explains the increased fluoride leaching from fluoride-bearing minerals in an acidic environment.

Table 3

Calculated Pearson's r values for groundwater samples

TurbidityColorClTotal HardnessTotal alkalinityTDSNO3NO2FpH
Turbidity          
Color 0.756         
Cl 0.306 0.151        
Total hardness 0.182 0.217 0.694       
Total alkalinity 0.062 0.196 0.159 0.645      
TDS 0.261 0.179 0.935 0.847 0.414     
NO3 0.207 0.150 0.202 0.297 0.305 0.243    
NO2 0.347 0.219 0.887 0.518 0.118 0.761 0.328   
F −0.062 −0.066 −0.031 −0.005 0.222 0.156 0.020 −0.037  
pH 0.129 0.155 0.028 0.060 −0.148 −0.013 0.087 0.065 − 0.729 
TurbidityColorClTotal HardnessTotal alkalinityTDSNO3NO2FpH
Turbidity          
Color 0.756         
Cl 0.306 0.151        
Total hardness 0.182 0.217 0.694       
Total alkalinity 0.062 0.196 0.159 0.645      
TDS 0.261 0.179 0.935 0.847 0.414     
NO3 0.207 0.150 0.202 0.297 0.305 0.243    
NO2 0.347 0.219 0.887 0.518 0.118 0.761 0.328   
F −0.062 −0.066 −0.031 −0.005 0.222 0.156 0.020 −0.037  
pH 0.129 0.155 0.028 0.060 −0.148 −0.013 0.087 0.065 − 0.729 

Note: Bold italic values show a strong (>0.75) correlation among parameters while bold values show a moderate (0.5–0.75) correlation among parameters.

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