Metoprolol behaviour in drinking water electrolysis using mixed oxide and boron doped diamond anodes

Bergmann, M.E.H.; Kresse, K.; Rollin, J.; Hartmann, J.

doi:10.2166/wpt.2010.032

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Research Article| June 01 2010

Metoprolol behaviour in drinking water electrolysis using mixed oxide and boron doped diamond anodes

M.E.H. Bergmann;

M.E.H. Bergmann

1Department of Applied Biosciences and Process Technology, Anhalt University, Bernburger Str. 55, D-06366 Koethen/Anh., Germany, E-mail: [email protected], [email protected]

Tel.: +49(0)3496 67 2313, Fax: +49(0)3496 67 2642, E-mail: [email protected]

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K. Kresse;

K. Kresse

1Department of Applied Biosciences and Process Technology, Anhalt University, Bernburger Str. 55, D-06366 Koethen/Anh., Germany, E-mail: [email protected], [email protected]

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J. Rollin;

J. Rollin

1Department of Applied Biosciences and Process Technology, Anhalt University, Bernburger Str. 55, D-06366 Koethen/Anh., Germany, E-mail: [email protected], [email protected]

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J. Hartmann

1Department of Applied Biosciences and Process Technology, Anhalt University, Bernburger Str. 55, D-06366 Koethen/Anh., Germany, E-mail: [email protected], [email protected]

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Water Practice and Technology (2010) 5 (2): wpt2010032.

https://doi.org/10.2166/wpt.2010.032

Metoprolol tartrate was electrolysed at 20°C in aqueous systems using mixed oxide and boron doped diamond anodes. Fast depletion was observed when chloride ions were components of the waters. Additional ions such as sulphate and nitrate decreased the oxidation rate. Higher chloride concentration and current densities up to 200 A m^-2 accelerated metoprolol destruction. 4-(2-methoxyethyle)-phenol and 3-chloro-4-hydroxyphenyle acidic acid were identified as reaction by-products.

BDD, chlorination, disinfection by-products, drinking water electrolysis, mixed oxide electrode, metoprolol, pharmaceutical residues

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