Arsenic is a toxic element found naturally in groundwater. Due to its carcinogenicity, risk for heart diseases and diabetes, arsenic needs to be removed from groundwater for potable application. ‘Anjili’ tree sawdust was chemically modified with ferric hydroxide and activated alumina (SFAA) and used as an adsorbent for the removal of arsenic from groundwater. The adsorbent was characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) to study the pore structure and surface functional groups. Effect of contact time, initial concentration, pH, particle size and temperature was studied. Arsenic adsorbed by SFAA followed Freundlich adsorption isotherm. Maximum sorption of arsenic by SFAA adsorbent occurred at pH 6.5. Arsenic sorption kinetics followed a pseudo-second-order model. The maximum sorption capacity at 303 K was found to be 54.32 mg/g for As(III) and 77.60 mg/g for As(V). Interference of other ions on the adsorption was in the order of PO43− > SO42− > HCO3− > NO3−.
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Research Article|
August 10 2015
Arsenic removal from groundwater by Anjili tree sawdust impregnated with ferric hydroxide and activated alumina Available to Purchase
P. Dhanasekaran;
1Fast Reactor Technology Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
E-mail: [email protected]
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P. M. Satya Sai;
P. M. Satya Sai
2Waste Immobilization Plant, Bhabha Atomic Research Centre, Kalpakkam, 603102, India
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C. Anand Babu;
C. Anand Babu
3Sri Venkateswara College of Engineering, Sriperumbudur, 602105, India
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R. Krishna Prabhu;
R. Krishna Prabhu
4Radioactive Chemical Laboratory, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
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K. K. Rajan
K. K. Rajan
1Fast Reactor Technology Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
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Water Supply (2016) 16 (1): 115–127.
Article history
Received:
March 02 2015
Accepted:
July 28 2015
Citation
P. Dhanasekaran, P. M. Satya Sai, C. Anand Babu, R. Krishna Prabhu, K. K. Rajan; Arsenic removal from groundwater by Anjili tree sawdust impregnated with ferric hydroxide and activated alumina. Water Supply 1 February 2016; 16 (1): 115–127. doi: https://doi.org/10.2166/ws.2015.119
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