The objective of this study is to quantify the effects of humic acid solution infiltration on the transport of organochlorine pesticides (OCPs) in soil columns using a three-phase transport model. From experimental results, it is found that the dissolved organic carbon enhances the transport of OCPs in the soil columns. In the OCPs-only column, the concentration profiles of OCPs can be simulated well using a two-phase transport model with numerical method or analytical solution. In the OCPs-DOC column, the migrations of aldrin, DDT and its daughter compounds are faster than those in the OCPs-only column. The simulation with the three-phase model is more accurate than that with the two-phase model. In addition, significant decrease of the fluid pore velocities of the OCPs-DOC column was found. When DOC leachate is applied for remediation of soil or groundwater pollution, the decrease of mean pore velocities will be a crucial affecting factor.

Dissolved organic carbon (DOC), humic acid, hydrophobic organic contaminants, organochlorine pesticides (OCPs), soil column, partition coefficient, three-phase transport model
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