The kinetics of removal of zinc ions from aqueous solutions by a modified acrylnitrile copolymer containing carboxyl and amino groups has been investigated. The dependence of the rate of removal on the intensity of stirring, the size of the sorbent's particles, the initial concentration of metal ions and the temperature of the solution have been established. Attempts have been made to identify the rate limiting step and to determine the batch kinetic parameters. The limiting conditions of the transition from external to intraparticle diffusion step of mass transfer in a sorption system have been determined. The coefficients of intraparticle diffusion and the energy of activation of the sorption process have been established. The data obtained in this work show that the modified polymer with a high sorption capacity and very good kinetic characteristics can be successfully used for removal of heavy metal ions from water solutions and industrial wastewaters.
Research Article|April 01 1999
R. Y. Stefanova; Kinetics of removal of zinc ions from aqueous solutions by a modified acrylnitrile copolymer. Water Sci Technol 1 April 1999; 39 (8): 139–146. doi: https://doi.org/10.2166/wst.1999.0406
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