Improper handling of jet fuel at abandoned military bases has resulted in heavy pollution of the soil and groundwater. Experimental research of photocatalytical oxidation (PCO) of jet fuel aqueous extract and aqueous solutions of de-icing agents was undertaken. The influence of different parameters - pH, concentration of substances to be oxidised, presence of inorganic admixtures, effect of OH• radical generators - on the PCO of solutions of de-icing agents and jet fuel aqueous extract was determined. The role of OH• radicals was found to be less important in determining the PCO rate. The PCO of organic pollutants was also investigated using a catalyst immobilised onto the surface of buoyant hollow glass micro-spheres. Attached titanium dioxide (TiO2) showed lower photocatalytical activity than when suspended in slurry, although it allows waters to be treated in simple shallow ponds without intensive stirring. The biodegradability of aqueous solutions of de-icing agents and jet fuel aqueous extract increased as PCO proceeded.
Photocatalytical oxidation of de-icing agents in aqueous solutions and aqueous extract of jet fuel
Krichevskaya M., Malygina T., Preis S., Kallas J.; Photocatalytical oxidation of de-icing agents in aqueous solutions and aqueous extract of jet fuel. Water Sci Technol 1 September 2001; 44 (5): 1–6. doi: https://doi.org/10.2166/wst.2001.0239
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