More stringent water quality parameters in the Annex of the Water Framework Directive 2000/60/EC led to the introduction of “Maximum Tolerable Risk concentrations” (MTR-values) in the national legislation in The Netherlands (Vierde Nota Waterhuishouding). The MTR-values give limitations for the concentrations of e.g. heavy metals (HM's) but also for nutrients: Ntot <2.2 mg/l, Ptot <0.15 mg/l. Investigations of HM removal during denitrifying flocculation filtration are conducted on the effluent of a typical modern Dutch WWTP. Because of low concentrations of HM's in the feed water, a cocktail of copper, nickel and zinc chloride (≈150–200 μg/l) is dosed before filtration. Preliminary jar tests and filtration tests with media filtration in pilot-scale and lab-scale are conducted. The results show high removal of nickel and zinc during jar tests with dosing of powdered activated carbon. During filtration tests at pilot-scale the bounded fraction of copper and zinc is highly removed. All three HM's are removed in the lab-scale activated carbon filter. After dosing, nickel is found mainly in the dissolved form, but it is removed in the lab-scale activated carbon filter. The removal of HM's via adsorption subsequently leads to a discussion on the toxicity of HM's and their bio-availability.
Research Article|November 01 2006
Behaviour of heavy metals during tertiary bio-filtration
Water Sci Technol (2006) 54 (10): 209-216.
V. Miska, K. Gorter, H.W.H. Menkveld, R. Neef, J.H.J.M. van der Graaf; Behaviour of heavy metals during tertiary bio-filtration. Water Sci Technol 1 November 2006; 54 (10): 209–216. doi: https://doi.org/10.2166/wst.2006.879
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