Advanced oxidation processes assisted with natural solar radiation in CPC type reactors (parabolic collector compound), was applied for the degradation of three azo dyes: acid orange (AO7), acid red 151 (AR151) and acid blue 113 (AB113). Fenton, Fenton like and ferrioxalate-type complexes showed to be effective for degrade the azo linkage and moieties in different extensions. Initially, the best dose of reagents (Fe3 + -H2O2) was determined through a factorial experimental design, next, using response surface methodologies, the reagent consumption was reduced up to 40%, maintaining in all cases high decolourisation percentages (>98%) after 60 min. of phototreatment. In this work, it was also studied the effect of concentration changes of the influent between 100–300 mg/L and the operation of the photocatalytic process near neutral conditions (pH 6.0–6.5) by using ferrioxalate type complex (FeOx).
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Research Article|
March 01 2009
Solar photoassisted advanced oxidation process of azo dyes Available to Purchase
D. Prato-Garcia;
1Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro, 76230, México E-mail: [email protected]
E-mail: [email protected]
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G. Buitrón
G. Buitrón
1Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro, 76230, México E-mail: [email protected]
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Water Sci Technol (2009) 59 (5): 965–972.
Citation
D. Prato-Garcia, G. Buitrón; Solar photoassisted advanced oxidation process of azo dyes. Water Sci Technol 1 March 2009; 59 (5): 965–972. doi: https://doi.org/10.2166/wst.2009.071
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