A distillation-assisted catalytic oxidation (DACO) process under low temperature (100 °C) and atmospheric pressure was investigated to treat heavily contaminated wastewater from oil refining industry. The DACO experiments were carried out in a distillation batch reactor, using CuO/γ-A12O3 as catalyst. The experimental temperature was kept at 100 °C and H2O2 oxidant was supplied into the reactive system with 200 mL/L. The results demonstrated that more than 92.2% of chemical oxygen demand removal was obtained and the absorbance of the refinery wastewater after treatment was zero, indicating significant decolorization efficiency for the solution. The research of life and stability showed that the catalyst had a good stability. The present study indicates that this DACO approach may have a significant application potential for industrial wastewater treatment.
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Research Article|
June 01 2011
Treatment of petroleum refinery wastewater by distillation-assisted catalytic oxidation under low temperature and low pressure Available to Purchase
Xiaoming Gao;
Xiaoming Gao
1Department of Chemical Engineering, Northwest University, Xi'an, Shaanxi 710069, China
2Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
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Wenhong Li;
1Department of Chemical Engineering, Northwest University, Xi'an, Shaanxi 710069, China
E-mail: [email protected]
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Feng Fu;
Feng Fu
2Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
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Dong Li;
Dong Li
1Department of Chemical Engineering, Northwest University, Xi'an, Shaanxi 710069, China
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Zhenheng Cao;
Zhenheng Cao
2Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
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Jiwu Wang
Jiwu Wang
2Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China
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Water Sci Technol (2011) 63 (11): 2713–2718.
Citation
Xiaoming Gao, Wenhong Li, Feng Fu, Dong Li, Zhenheng Cao, Jiwu Wang; Treatment of petroleum refinery wastewater by distillation-assisted catalytic oxidation under low temperature and low pressure. Water Sci Technol 1 June 2011; 63 (11): 2713–2718. doi: https://doi.org/10.2166/wst.2011.549
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