This study utilises a UV/TiO2 system to decolorise C.I. Reactive Black 5 (RB5). The effects of TiO2 dosage, pH, RB5 concentration and light power on the decolorisation efficiency using the UV/TiO2 system were determined. IO4− was employed as an oxidant to increase the photodegradation efficiency of UV/TiO2. The decolorisation rate constants (k) of RB5 in the UV/TiO2 system are consistent with pseudo-first-order kinetics. The k values of 0.1, 0.5, 1.0 and 2.0 g/l TiO2 were 0.53, 0.52, 0.69 and 0.68 h−1, respectively. The rate constant increases with decreasing pH from 10 to 4. The decolorisation rate approximates linear relationship with RB5 concentration, as given by k=1.05[1/RB5]0.98; it varies nonlinearly with light power, as given by k=0.178[power]0.63. The experimental results reveal that the rate of decolorisation obtained using UV/TiO2/IO4− exceeds that obtained using UV/TiO2.
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Research Article| March 01 2011
Effects of operational parameters on decolorisation of C.I. Reactive Black 5 in UV/TiO2 system
C. H. Wu;
C. Y. Kuo;
Water Sci Technol (2011) 63 (5): 1032–1036.
C. H. Wu, C. Y. Kuo, P. K. A. Hong; Effects of operational parameters on decolorisation of C.I. Reactive Black 5 in UV/TiO2 system. Water Sci Technol 1 March 2011; 63 (5): 1032–1036. doi: https://doi.org/10.2166/wst.2011.286
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