Biochemical methane potential (BMP) tests have been carried out on sewage sludge from two wastewater treatment plants to assess the effect of additives (FeCl3 and two cationic polyelectrolytes) used in sludge dewatering. BMP tests were also carried out on the concentrated solid phase from the enzymic hydrolysis pre-treatment (42 °C, 48 h). FeCl3 had no significant effect on specific methane production, obtaining 242–246 LCH4/kgVSo. The effect of the combination of polyelectrolyte and FeCl3 depended on the polyelectrolyte and the sludge, but generally led to an increase in specific methane production (25–40%). When enzymic hydrolysis was applied as a pre-treatment, specific methane production increased from 6.8% in the sludge containing FeCl3 to 20% in the sludge without FeCl3, although the increases were not statistically significant. In terms of LCH4/kgVSrem, a general improvement was achieved both by means of additives and by enzymic hydrolysis. However, this improvement was only significant in the case of sludge which had undergone previous enzymic hydrolysis (62%) and in the untreated sludge containing a polyelectrolyte and FeCl3 (24%). Cationic polyelectrolytes inhibited solid–liquid separation during enzymic hydrolysis and, although the presence of only FeCl3 did not affect this separation, a significant decrease (32%) in LCH4/kgVSrem was observed.
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Research Article|
October 01 2013
Influence of conditioning agents and enzymic hydrolysis on the biochemical methane potential of sewage sludge
Elena Marañón;
Elena Marañón
1University Institute of Industrial Technology of Asturias, University of Oviedo, 33203 Gijón, Spain
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Luis Negral;
1University Institute of Industrial Technology of Asturias, University of Oviedo, 33203 Gijón, Spain
E-mail: negralluis@uniovi.es
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Yolanda Fernández-Nava;
Yolanda Fernández-Nava
1University Institute of Industrial Technology of Asturias, University of Oviedo, 33203 Gijón, Spain
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Leonor Castrillón
Leonor Castrillón
1University Institute of Industrial Technology of Asturias, University of Oviedo, 33203 Gijón, Spain
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Water Sci Technol (2013) 68 (7): 1622–1632.
Article history
Received:
January 16 2013
Accepted:
June 04 2013
Citation
Elena Marañón, Luis Negral, Yolanda Fernández-Nava, Leonor Castrillón; Influence of conditioning agents and enzymic hydrolysis on the biochemical methane potential of sewage sludge. Water Sci Technol 1 October 2013; 68 (7): 1622–1632. doi: https://doi.org/10.2166/wst.2013.413
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