The absorbances of different concentrations of Fe2+, Fe3+ and H2O2 were investigated by UV-visible spectrophotometry without separating the substances. The law of complex formation was studied by considering changes in the UV-vis spectra of mixtures of these three substances. The results show that upon eliminating the influence of the substrate, an iron-based complex was present in the Fenton reaction, which exhibited substantial absorbance from 190 to 500 nm. Therefore, the presence of an unknown complex in the Fenton oxidation process was verified and its concentration varied with a change in the concentration of hydrogen peroxide. This study provides a strong foundation for further studies into the mechanism of traditional hydroxyl radical theory of the Fenton reaction.
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Research Article|
January 22 2014
Analysis of a complex produced in the Fenton oxidation process Available to Purchase
Chang Wang;
1College of Marine Science and Engineering, Tianjin University of Science & Technology, Tianjin 300457, China
E-mail: [email protected]
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Siyue Zhang;
Siyue Zhang
1College of Marine Science and Engineering, Tianjin University of Science & Technology, Tianjin 300457, China
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Sakai Yuji;
Sakai Yuji
2Department of Environmental Chemical Engineering, Kogakuin University, Tokyo 192-0015, Japan
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Zongpeng Zhang
Zongpeng Zhang
1College of Marine Science and Engineering, Tianjin University of Science & Technology, Tianjin 300457, China
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Water Sci Technol (2014) 69 (5): 1115–1119.
Article history
Received:
September 09 2013
Accepted:
January 03 2014
Citation
Chang Wang, Siyue Zhang, Sakai Yuji, Zongpeng Zhang; Analysis of a complex produced in the Fenton oxidation process. Water Sci Technol 1 March 2014; 69 (5): 1115–1119. doi: https://doi.org/10.2166/wst.2014.019
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