Series of anionic flocculants with outstanding flocculation performance, poly(acrylic acid-co-acrylamide)/diatomite composite flocculants (PAAD) were successfully prepared through aqueous solution copolymerization and applied to flocculate from oil-field fracturing waste-water. The structure of PAAD was characterized by Fourier transform infra-red spectroscopy , 13C nuclear magnetic resonance and X-ray diffraction tests, and its properties were systematically evaluated by viscometer, thermogravimetry analysis and flocculation measurements. Furthermore, the influences of various reaction parameters on the apparent viscosity of flocculant solution were studied, and the optimum synthesis condition was determined. The novel composite flocculants exhibited outstanding flocculation properties. Specifically, the dosage of composite flocculants that could make the transmittance of treated wastewater exceed 90% was only approximately 12–35 ppm, which was far lower than that of conventional flocculants. Meanwhile, the settling time was lower than 5 s, which was similar to that of conventional flocculants. This was because PAAD flocculants had a higher absorption capacity, and larger chain extending space than conventional linear flocculants, which could refrain from the entanglement of linear polymer chains and significantly improve flocculation capacity.
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Research Article|
June 09 2015
A novel poly(acrylic acid-co-acrylamide)/diatomite composite flocculant with outstanding flocculation performance Available to Purchase
Kun Xu;
Kun Xu
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Yao Liu;
Yao Liu
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Yang Wang;
2Wuhan Research Institute of Materials Protection, Wuhan 430030, China
E-mail: [email protected]
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Ying Tan;
Ying Tan
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Xuecheng Liang;
Xuecheng Liang
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Cuige Lu;
Cuige Lu
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Haiwei Wang;
Haiwei Wang
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Xiusheng Liu;
Xiusheng Liu
2Wuhan Research Institute of Materials Protection, Wuhan 430030, China
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Pixin Wang
Pixin Wang
1Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
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Water Sci Technol (2015) 72 (6): 889–895.
Article history
Received:
December 15 2014
Accepted:
May 21 2015
Citation
Kun Xu, Yao Liu, Yang Wang, Ying Tan, Xuecheng Liang, Cuige Lu, Haiwei Wang, Xiusheng Liu, Pixin Wang; A novel poly(acrylic acid-co-acrylamide)/diatomite composite flocculant with outstanding flocculation performance. Water Sci Technol 1 September 2015; 72 (6): 889–895. doi: https://doi.org/10.2166/wst.2015.290
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