This study aimed to determine the best method to treat a textile effluent containing the dye basic blue 99 (BB). Treatments by the electrochemical and the Fenton processes were compared by means of a 23 experimental design, and the interaction of experimental conditions for BB oxidation were determined. The electrochemical treatment gave better results in the presence of NaCl as electrolyte and high current density (30 mA cm−2); the Fenton reaction provided better results at H2O2 and Fe2+ concentrations of 10 mg L−1 and 0.5 mmol L−1, respectively. Electrochemical treatment was 23 times faster than the Fenton reaction because formation of chlorinated species during electrooxidation significantly contributed to dye oxidation. Although the electrochemical process was more efficient, the resulting treated effluent was more toxic to Lactuca sativa germination and growth, which indicated some biotoxicity. Results demonstrated that both processes efficiently remediated effluents containing the dye BB, but they need to be combined with other processes to ensure complete adequacy of the effluent for disposal.
Efficiency and toxicity: comparison between the Fenton and electrochemical processes
Marcela Gomes Tavares, Danilo Henrique da Silva Santos, Sheyla Jaqueline Albuquerque Torres, Wagner Roberto Oliveira Pimentel, Josealdo Tonholo, Carmem Lucia de Paiva e Silva Zanta; Efficiency and toxicity: comparison between the Fenton and electrochemical processes. Water Sci Technol 19 September 2016; 74 (5): 1143–1154. doi: https://doi.org/10.2166/wst.2016.278
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