Selected organic pollutants are classified based on an intensive literature survey. Two wastewater parameters (COD and ammonium) and six selected organic pollutants (polycyclic aromatic hydrocarbons (PAH), diethylhexylphthalate (DEHP), estradiol (E2), ethinylestradiol (EE2), ethylenediamine tetraacetic acid (EDTA) and nitrilo triaceticacid (NTA)) are specified. As a result, for the first time representative concentrations in dry weather flow, surface runoff and effluent of wastewater treatment plants (WWTPs) in combined sewer systems (CSS) are stated. The second part of the paper presents a first estimation of main emission out of a combined sewer system and possible receiving water impacts in terms of (1) annual discharged loads calculated by pollution load simulations in a hypothetical catchment and (2) concentrations calculated in combined sewer overflows (CSO) discharges and resulting receiving water concentrations.